Biochars (BC) of spent coffee grounds, both pristine (SCBC) and impregnated with titanium oxide (TiO2@SCBC) were exploited as environmentally friendly and economical sorbents for the fluroquinolone antibiotic balofloxacin (BALX). Surface morphology, functional moieties, and thermal stabilities of both adsorbents were scrutinized using SEM, EDS, TEM, BET, FTIR, Raman, and TG/dT analyses. BET analysis indicated that the impregnation with TiO2 has increased the surface area (50.54 m2/g) and decreased the pore size and volume. Batch adsorption experiments were completed in lights of the experimental set-up of Plackett–Burman design (PBD). Two responses were maximized; the % removal (%R) and the adsorption capacity (qe, mg/g) as a function of four variables: pH, adsorbent dosage (AD), BALX concentration ([BALX]), and contact time (CT). %R of 68.34% and 91.78% were accomplished using the pristine and TiO2@SCBC, respectively. Equilibrium isotherms indicated that Freundlich model was of a perfect fit for adsorption of BALX onto both adsorbents. Maximum adsorption capacity (qmax) of 142.55 mg/g for SCBC and 196.73 mg/g for the TiO2@SCBC. Kinetics of the adsorption process were best demonstrated using the pseudo-second order (PSO) model. The adsorption-desorption studies showed that both adsorbents could be restored with the adsorption efficiency being conserved up to 66.32% after the fifth cycles.
Monitoring exhaled breath is a safe, noninvasive method for determining the health status of the human body. Most of the components in our exhaled breath can act as health biomarkers, and they help in providing information about various diseases. Nitric oxide (NO) is one such important biomarker in exhaled breath that indicates oxidative stress in our body. This work presents a simple and noninvasive quantitative analysis approach for detecting NO from exhaled breath. The sensing is based on the colorimetric assisted detection of NO by m-Cresol Purple, Bromophenol Blue, and Alizaringelb dye. The sensing performance of the dye was analyzed by ultraviolet–visible (UV–Vis) spectroscopy. The study covers various sampling conditions like the pH effect, temperature effect, concentration effect, and selective nature of the dye. The m-Cresol Purple dye exhibited a high sensitivity towards NO with a detection limit of ~0.082 ppm in the linear range of 0.002–0.5 ppm. Moreover, the dye apprehended a high degree of selectivity towards other biocompounds present in the breath, and no possible interfering cross-reaction from these species was observed. The dye offered a high sensitivity, selectivity, fast response, and stability, which benchmark its potential for NO sensing. Further, m-Cresol Purple dye is suitable for NO sensing from the exhaled breath and can assist in quantifying oxidative stress levels in the body for the possible detection of COVID-19.
Volatile organic compounds (VOCs) have been recognized as one of the primary trace segments of atmospheric air pollutants. The change in the level of VOCs in the surrounding environment can lead to chronic health issues, respiratory problems, nerve system disorder, and toxicity in kidneys/liver. Thus, monitoring of VOCs concentration in the surrounding environment is significant for avoiding serious health problems. Herein, copper oxide (CuO) nanoparticle and carbon nanotube (CNT) nanocomposite (NC) are presented for the efficient detection of VOCs. The scalable sol‐gel method is adopted for the controlled growth of CNT/CuO NC. The structural, elemental, and morphological analysis is performed by XRD, FTIR spectroscopy, and SEM characterization, respectively. The VOCs sensor was fabricated by drop‐casting the as‐synthesized CNT/CuO NC on interdigitated electrodes (IDEs). The CNT/CuO sensing response is analyzed for six VOCs that include toluene, methanol, acetone, chloroform, xylene, and benzene. The CNT/CuO response towards different VOCs is investigated with respect to change in resistance of the material in the presence of test VOC and in an inert atmosphere. In comparison to other VOCs, the sensor exhibits high sensitivity toward benzene. The estimated change in relative resistance (AR) for benzene is ≈0.62% for 500 ppm concentration. Moreover, the sensor apprehended a detection of benzene with a concentration as low as 5 ppm. The as‐synthesized CNT/CuO NC offers high sensitivity and low detection limit, which benchmark its potential for benzene detection.
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