The continuous deterioration of the environment due to extensive industrialization and urbanization has raised the requirement to devise high-performance environmental remediation technologies. Membrane technologies, primarily based on conventional polymers, are the most commercialized air, water, solid, and radiation-based environmental remediation strategies. Low stability at high temperatures, swelling in organic contaminants, and poor selectivity are the fundamental issues associated with polymeric membranes restricting their scalable viability. Polymer-metal-carbides and nitrides (MXenes) hybrid membranes possess remarkable physicochemical attributes, including strong mechanical endurance, high mechanical flexibility, superior adsorptive behavior, and selective permeability, due to multi-interactions between polymers and MXene's surface functionalities. This review articulates the state-of-the-art MXene-polymer hybrid membranes, emphasizing its fabrication routes, enhanced physicochemical properties, and improved adsorptive behavior. It comprehensively summarizes the utilization of MXene-polymer hybrid membranes for environmental remediation applications, including water purification, desalination, ion-separation, gas separation and detection, containment adsorption, and electromagnetic and nuclear radiation shielding. Furthermore, the review highlights the associated bottlenecks of MXene-Polymer hybrid-membranes and its possible alternate solutions to meet industrial requirements. Discussed are opportunities and prospects related to MXene-polymer membrane to devise intelligent and next-generation environmental remediation strategies with the integration of modern age technologies of internet-of-things, artificial intelligence, machine-learning, 5G-communication and cloud-computing are elucidated.The ORCID identification number(s) for the author(s) of this article can be found under
Summary
Photovoltaic (PV) technology got much attention in the past few decades in developing advanced and environment friendly solar cells (SCs). However, high cost, unstable nature, and low efficiency are major limitations towards commercialization of SCs. To overcome the issues, two‐dimensional materials (2DMs) have been exploited due to low cost, high catalytic activity, fast charge separation, and better electrochemical performance. The review emphasis on (a) the electrochemical performance of graphene and transition metal dichalcogenides (TMDCs) as a hole transport layer (HTL) in SCs and (b) to explore low‐cost and effective counter electrode (CE) based on graphene and TMDCs for dye‐sensitized solar cell (DSSC). The review presents a comparative analysis of 2DMs as HTL and CE to attain highly efficient and low‐cost PV devices. Multiple combinations of the material with graphene, graphene oxide (GO), reduced graphene oxide (rGO), tungsten disulfide (WS2), molybdenum disulfide (MoS2) as HTL, and CE material in PV cells are discussed and comparatively analyzed. Numerous strategies are briefly discussed to enhance the efficiency of SCs by utilizing graphene and TMDCs based HTL and CEs. The review focuses on the recent progress in developing low‐cost and highly efficient PV devices by using 2DMs. Our study reveals that GO/PEDOT:PSS demonstrate a maximum power conversion efficiency (PCE) of 13.1% when fabricated at different revolutions. Moreover, our statistical analysis unveils that efficiency of the cell can be enhanced by optimizing the layer thickness, which provide a route to develop highly efficient and better performance SCs that can be exploited for future commercial applications.
Energy storage is becoming a critical issue due to the diminishing availability of fossil fuels and the intermittent nature of current renewable energy sources. As a result, thermal management (TM) and thermal energy systems have gained significant attention due to their crucial roles in various industries. Among the different TM materials, MXenes, a member of the transition metal carbide/nitride family, have emerged as a promising material due to their unique 2D nanostructure, changeable surface chemistry, high electrical/thermal conductivity, light absorptivity, and low infrared emissivity. This review outlines the synthesis methods of MXenes and their various features and applications in thermal management. These 2D materials exhibit outstanding optical and thermal properties, making them suitable for thermal energy generation and storage. The study also covers the potential applications of MXene in the desalination industry, hybrid photovoltaic thermal systems, solar energy storage, electronics, and other thermal management related industries. The findings suggest that MXene-based TM materials have remarkable features that significantly influence thermal energy storage and conversion and present opportunities for further research in efficiently using these materials.
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