3-Alkyl(aryl)-4-amino-4,5-dihydro-1H-1,2,4-triazol-5-ones (1) reacted with 5-methylfuran-2-carboxyaldehyde to afford the corresponding 3-alkyl(aryl)-4-(5-methyl-2-furylmethylenamino)-4,5-dihydro-1H-1,2,4-triazol-5-ones (2). Four newly synthesized compounds have been characterized by elemental analyses, IR, 1 H-NMR,
13C-NMR and UV spectral data. In addition, isotropic 1 H-and 13 C-nuclear magnetic shielding constants of compounds 3 were calculated by employing the direct implementation of the gaugeincluding-atomic-orbital (GIAO) method at the B3LYP density functional and HF levels of the theory. The geometry of each compound has been optimized using a 6-311G basis set. Nuclear shielding constants were also calculated by using 6-311G basis set. Theoretical values are compared to the experimental data.
As the most commonly used construction material, concrete produces extreme amounts of carbon dioxide (CO2) yearly. For this resulting environmental impact on our planet, supplementary materials are being studied daily for their potentials to replace concrete constituents responsible for the environmental damage caused by the use of concrete. Therefore, the production of bio-concrete has been studied by utilizing the environmental and structural benefit of the bacteria, Bacillus subtilis, in concrete. This bio-concrete is known as self-healing concrete (SHC) due to its potential to trigger biochemical processes which heal cracks, reduce porosity, and improve strength of concrete throughout its life span. In this research paper, the life cycle assessment (LCA) based on the environmental impact indices of global warming potential, terrestrial acidification, terrestrial eco-toxicity, freshwater eco-toxicity, marine eco-toxicity, human carcinogenic toxicity, and human non-carcinogenic toxicity of SHC produced with Bacillus subtilis has been evaluated. Secondly, predictive models for the mechanical properties of the concrete, which included compressive (Fc), splitting tensile (Ft), and flexural (Ff) strengths and slump (S), have been studied by using artificial intelligence techniques. The results of the LCA conducted on the multiple data of Bacillus subtilis-based SHC mixes show that the global warming potential of SHC-350 mix (350 kg cement mix) is 18% less pollutant than self-healing geopolymer concrete referred to in the literature study. The more impactful mix in the present study has about 6% more CO2 emissions. In the terrestrial acidification index, the present study shows a 69–75% reduction compared to the literature. The results of the predictive models show that ANN outclassed GEP and EPR in the prediction of Fc, Ft, Ff, and S with minimal error and overall performance.
An extensive study in blended cement pastes that comprised two different experimental settings was carried out so as to analyse the hydration process and compressive strength evolution up to 91 days. The aim of this study was to understand the hydration process using zeolite-rich tuffs and siltstone as supplementary cementitious materials at low water-to-binder ratio (W/B = .3) under wet curing condition. It was observed that there were two competing reactions, i.e. pozzolanic reaction and carbonation, during the hydration process, thus leading to a decrease in the content of calcium hydroxide (CH); however, carbonation played a more important role than the pozzolanic reaction in consuming it at the given W/B ratio. The total amount of CH consumed by pozzolanic reaction was likely around 8%, while carbonation transformed around 19% of the total amount of CH at 91 days. Although fully hydrated cement paste incorporates .23 g of water per g of cement, only 60% of this value was used at such a W/B ratio. In addition, the amount of normalised water in hydrates increased as the dosage increased by factor of .158% per 1% of dosage. Finally, the optimal dosages at which Zeo1, Zeo2 and Limo showed the highest compressive strength were in the ranges of 12.5-15%, 17.5-20% and 10-12.5%, respectively .
Ecuador is a country
where shrimp production is one of its primary
industries. It generates annually about 72,000 tons of wastes in the
form of shrimp shells. Therefore, using this waste as a raw material
resource to produce chitosan, a biopolymer, is established. An environmental
and economic performance study is carried out as a possible investment
report, where a conceptual design of the process is defined and a
financial viability report is obtained. An environmental impact report
establishes the degree of harm to the environment. The economic viability
study considered costs related to capital and operation to process
5000 tons of shrimp shells each year. On the other hand, a life cycle
assessment was performed to obtain the environmental impact for 1
kg of chitosan produce, where a cradle-to-gate approach was established.
Results showed that this new industry has a net present value of 10.38
million USD, a rate of return of 67.31%, and a payback period of 3.13
years. Additionally, it was calculated that the environmental impact
with a higher normalized value was the human noncarcinogenic toxicity.
It is concluded that the production of chitosan in Guayas-Ecuador
is economically viable and cost-competitive in the market, and it
represents an industrial activity with no considerable environmental
impacts.
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