Recent studies of Minnesota's sand plains indicate that ground-water chemistry is related to agricultural practices. Surficial sand-plain aquifers cover 8,000,000 acres of Minnesota and are a major source of water for domestic use, irrigation, and some municipal systems. The sand-plain aquifers consist of sand and gravel deposits that are from 20 to greater than 100 feet thick and are covered by a thin sandy loam that generally is less than 2 feet thick. Sand-plain aquifers are recharged by the downward percolation of precipitation through the soil root zone and the unsaturated zone in the sand to the water table. The water table is the upper surface of the zone of saturation and forms the top of the sand-plain aquifer. Sand-plain aquifers are susceptible to contamination by agricultural chemicals (fertilizers and pesticides), if downward-percolating recharge water contains these chemicals. The concentrations of nitrate, pesticides, and some other chemical constituents fluctuate seasonally and differ with depth below the water table (Anderson, 1989). Despite the availability of water-quality data for about 260 wells that were collected during previous studies in three U.S. Geological Survey (USGS) project areas in Minnesota, it is not known how concentrations of agricultural chemicals in ground water relate to the rate and timing of fertilizer and pesticide application or to the tillage practices used. Field-scale research is needed to determine the effects of different farming practices on the concentrations of nitrate, pesticides, and other agricultural chemicals in ground water in the unsaturated and saturated zones.-
Water quality in the 1,700-square-mile Anoka Sand Plain aquifer is affected by irrigated and nonirrigated agriculture and by residential land use. Concentrations of sulfate, chloride, nitrite plus nitrate nitrogen, and pesticides in ground water are related to human activities; nitrite plus nitrate nitrogen concentrations are affected more than concentrations of other chemical constituents. Of the water samples collected from 100 wells during this study, samples from 30 wells had concentrations of nitrite plus nitrate nitrogen greater than 10 mg/L (milligrams per liter), which is the limit recommended for drinking water by the Minnesota Pollution Control Agency. Analysis of 360 water samples indicated that the median concentrations of nitrite plus nitrate nitrogen for undeveloped, nonirrigated-cultivated, irrigated, and residential lands were 0.22,2.0,5.3, and 4.2 mg/L, respectively. Differences in nitrite plus nitrate nitrogen concentrations at various depths below the water table were statistically significant. Median concentrations of nitrite plus nitrate nitrogen in groundwater samples less than 10 feet, 10 to 20 feet, and more than 20 feet below the water table were 5.1 mg/L, 2.7 mg/L, and less than 0.1 mg/L, respectively. Seasonal fluctuations in nitrite plus nitrate nitrogen concentrations at many wells were as great or greater than long-term change; however, the springtime median concentration of nitrite plus nitrate nitrogen increased steadily from 1984 (4.8 mg/L) through 1987 (5.5 mg/L). Triazine herbicides were detected in 11 of 18 samples analyzed for pesticides. Concentrations of atrazine were less than the 3 (J-g/L maximum contaminant level set for atrazine by the Minnesota Department of Health and by the U.S. Environmental Protection Agency.
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