Evaporation of water droplets on a superhydrophobic substrate, on which the contact line is pinned, is investigated. While previous studies mainly focused on droplets with contact angles smaller than 90 • , here we analyze almost the full range of possible contact angles (10 • -150 • ). The greater contact angles and pinned contact lines can be achieved by the use of superhydrophobic Carbon Nanofiber substrates. The time-evolutions of the contact angle and the droplet mass are examined. The experimental data is in good quantitative agreement with the model presented by Popov (Physical Review E 71, 2005), demonstrating that the evaporation process is quasi-static, diffusion-driven, and that thermal effects play no role. Furthermore, we show that the experimental data for the evolution of both the contact angle and the droplet mass can be collapsed onto one respective universal curve for all droplet sizes and initial contact angles.

Droplets impacting on a superheated surface can either exhibit a contact boiling regime, in which they make direct contact with the surface and boil violently, or a film boiling regime, in which they remain separated from the surface by their own vapor. The transition from the contact to the film boiling regime depends not only on the temperature of the surface and the kinetic energy of the droplet, but also on the size of the structures fabricated on the surface. Here we experimentally show that surfaces covered with carbon-nanofibers delay the transition to film boiling to much higher temperatures compared to smooth surfaces. We present physical arguments showing that, because of the small scale of the carbon fibers, they are cooled by the vapor flow just before the liquid impact, thus permitting contact boiling up to much higher temperatures than on smooth surfaces. We also show that as long as the impact is in the film boiling regime, the spreading factor of impacting droplets is consistent with the We(3/10) scaling (with We being the Weber number) as predicted for large We by a scaling analysis.

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