Palladium nanoparticles display fascinating electronic, optical and catalytic properties, thus they can be used for various applications such as sensor fabrication. Conducting polymers such as polyaniline have also been widely used in sensor technology due to its cost effectiveness, versatility, and ease of synthesis. In this research, attention was given to unify the exceptional properties of these two materials and construct palladium nanoparticle coated polyaniline films to detect hydrogen and moisture. Electrochemical polymerization of aniline was carried out on gold sputtered epoxy resin boards. Polyaniline film was generated across a gap of 0.2 mm created by a scratch made on the gold coating prior to electrochemical polymerization. A palladium nanoparticle dispersion was prepared using sonochemical reduction method and coated on to polyaniline film using drop-drying technique. Polyaniline only films were also fabricated for comparative analysis. Sensitivity of films towards humidity and hydrogen was evaluated using impedance spectroscopy in the presence of the respective species. According to the results, polyaniline films exhibited an impedance drop in the presence of humidity and the response was significantly improved once palladium nanoparticles were incorporated. Interestingly, polyaniline only films did not respond to hydrogen. Nevertheless, palladium nanoparticle coated polyaniline films exhibited remarkable response towards hydrogen.
This study used the groundwater quality index (GWQI) and Geographic Information System (GIS) techniques to examine groundwater quality in the western coastal region of Sri Lanka. The spatial and temporal variation of 18 groundwater samples' physiochemical parameters [pH, electrical conductivity (EC), turbidity, total dissolved solids (TDS), sodium (Na+), potassium (K+), calcium (Ca2+), magnesium (Mg2+), chloride (Cl−), and bicarbonate (HCO3−)] were studied. According to the WHO and SLS, 11% of samples had EC levels that were above the acceptable range, and 22% had turbidity levels that were beyond the acceptable range. When considering, pH, TDS, other cations, and anions analyzed in the study were still below the standard permissible levels. The western coastline region, as well as several areas of the central study region, had significant concentrations of physicochemical parameters. According to the GWQI, water was consumable in 77.78% of locations in the study region and unsatisfactory in 22.22%. Furthermore, due to severe coastal erosion, the quality of groundwater in the study region is deteriorating, therefore maintaining a comprehensive groundwater management strategy to promote sustainable water consumption is imperative.
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