Fibers of poly(p‐phenylene terephthalamide) (PPTA) have a fibrillar morphology, the individual fibrils having a high proportion of extended chains passing through periodic defect layers. A pleat structure is superimposed. The fibers are fully crystalline (within the limits of determination) with a small fraction of randomly oriented crystalline material. The major distinction between PPTA and conventional fibers lies in the high level of extended chains passing through the defect layers of the former structure. These extended chains result in crystallographic register being maintained between adjacent ordered zones. Quantitatively, a measure of this order is obtained from a comparison of the correlation length, obtained from meridional x‐ray peak widths, and the defect spacing. In conventional fibers the defect spacing, i.e., long period, is longer than the correlation length (i.e., crystal size). In PPTA, the analog of the long period, the defect spacing (about 35 nm) is smaller than the correlation length, which is over 80 nm.
Aluminium alloys play an important role in overhead power transmission applications. All-aluminium alloy conductor cables require increasingly hard-to-achieve combinations of high tensile strength and high electrical conductivity. The problem is that a high strength is normally associated with a reduced electrical conductivity. Both heat-treatable 6xxx series aluminium alloys and work-hardening 1xxx series aluminium alloys are important contenders for these applications. By contrast, the addition of rare earths and/or transition metals to aluminium may provide further opportunities to achieve improved combinations of precipitation hardening, substructural hardening and elevated temperature stability. In this work, strength and electrical conductivity relationships are investigated for a range of 6xxx series aluminium alloys and an Al-Sc alloy. The Al-Sc alloy was produced by means of a direct laser metal deposition process that allowed more Sc to be placed into solid solution than by conventional casting or solution treatment. The paper explores the relative effects of composition, cold working and age hardening on the balance of strength and electrical conductivity, including examples of how improved combinations of both strength and conductivity can be achieved.
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