The equilibrium conditions of the two decomposition reactions of carbonyl sulphide have been further investigated. The reaction leading to carbon dioxide is shown to be peculiarly susceptible to the nature of the vessel wall, and the rate of the reaction has been measured under various conditions. A method has been devised for measuring the rate of the fast reaction leading to carbon mdnoxide, and a number of velocity values have been obtained. The disproportionation of carbon monoxide, considered as a possible side reaction, is shown not to occur in the range of conditions studied.THE thermal decomposition of carbonyl sulphide (COS) into carbon monoxide and sulphur was described by Than
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