The kinetic energy released in unimolecular reactions of a number of mono-substituted pyridines has been compared in the two field-free regions. A significant time dependence in cases of H, loss from molecular and fragment ions has been observed. Further, the average kinetic energy release ⟨T⟩ and the kinetic energy release distribution function n(T), upon fragmentation for the Gaussian and composite peaks, have been determined.
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