H. E. Gunning scite author profile

The reaction of H atoms, produced by the mercury photosensitized decomposition of H2, with COS was investigated in the temperature range 27-252°. The only primary reaction of importance is H + COS -* CO + SH (1). The rate coefficient of reaction 1 was determined in competition with the reaction H + H2S -*• H2 + SH to have the value k\ = (9.1 ± 1.2) X 1012 exp((-3900 ± 370)/RT) cc mol-1 sec-1.

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H. E. Gunning

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Reactions of sulfur atoms. XI. Intermediacy of a hybrid .pi.-thiacyclopropane in the addition reactions to olefins and in the thermal decomposition of episulfides

Electron spin resonance study of free radicals in Athabasca asphaltene

Reactions of sulfur atoms. X. Addition to carbon-carbon triple bonds and the formation of thiirenes

Abstraction of sulfur atoms from carbonyl sulfide by atomic hydrogen

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