This paper aims to numerical study of the experimental spectrum, in the context of the diagnosis of solid materials by spectroscopy; the resulting spectrum of fluorine plasma has beenanalyzed. The plasma is generated after the sublimation of the solid sample the fluorine by Laser Induced Breakdown Spectroscopy (LIBS technique). The theoretical spectra and the electronic temperature of a obtained plasma have been calculated, this temperature (1.92 eV) is well matched to the laboratory plasma criteria. The main results also are showed that the resulting medium consisted of 96.63% Calcium and 3.36% Fluor.
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