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Problem statement: Systematic series of ZnO-TeO 2 glasses with mole fraction of 0.10-0.40 ZnO content with an interval of 0.05 were studied to obtain their physical and optical properties. Approach: All the glass samples were synthesized by rapid melting quenching method under controlled conditions, while their refractive indices (n) were measured by the EL X-02C high precision ellipsometer. The room temperature absorption of all glass samples were determined using Camspec M350 double beam UV-visible spectrophotometer. The infrared (IR) spectra of each glass samples were recorded with Thermo Nicolet Fourier Transform-Infrared (FT-IR) spectrophotometer. Their physical properties were measured and the amorphous nature was confirmed by the x-ray diffraction technique. Results: The increase of refractive index of the TeO 2 -ZnO glasses with the addition of ZnO was best explained in terms of either electron density or polarizability of the ions. The absorption edge shift to higher energy (shorter wavelength) with increasing ZnO content was observed in this glass. The optical band gap (E opt ) of zinc tellurite glass decreases with increasing of ZnO content probably due to the increment of Non-Bridging Oxygen (NBO) ion contents which eventually shifted the band edge to lower energies. Conclusion/Recommendation: The physical and optical properties of zinc tellurite glasses were found generally affected by the changes in the glass composition. FTIR spectra of zinc tellurite glass revealed broad, weak and strong absorption bands in the investigated range of wave numbers from 4000-400 cm −1 which associated with their corresponding bond modes of vibration and the glass structure. The addition of ZnO into TeO 2 glass network shifted the major band from 626 cm −1 (for pure TeO 2 glass) to the band at around 669 cm −1 .

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Willemite is an inorganic semiconductor material used for optoelectronic applications. The present study purposes a new polymer thermal treatment method involving calcination temperature to fabricate the willemite nanoparticles. The effects of polyvinylpyrrolidone (PVP) on the structural and optical properties of the material were thoroughly investigated. Thermogravimetric and its derivative confirmed the decomposition behavior of PVP. The minimum calcination temperature to decompose PVP was appraised at 740°C. The FTIR and the Raman analyses confirmed the presence of organic source before the calcination process and the formation of the crystalline structure of the willemite nanoparticles after the heat treatment. The optimum PVP concentration in this study based on the FTIR results was found to be 40 g L-1. This is the minimum concentration at which the willemite nanoparticles remained pure with homogenous distribution. X-ray diffraction analysis of the PVP samples before calcination was confirmed to be amorphous, and upon calcination between 800 and 1000°C, an a-willemite phase was obtained. The morphology and the average particle size were determined with FESEM and HR-TEM analysis. The average particle size is between 23.8 and 36.7 nm. The optical energy band was found to be increasing from 5.24 to 5.32 eV with the corresponding increase in PVP concentration from 20 to 50 g L-1. The findings in this study provides a new pathway to understand the effects of PVP concentrations on the structural and optical properties of willemite semiconductor nanoparticles as it may have key potential applications for future optoelectronic devices.

Niobium-containing tellurite glass with starting composition of (90 − x)TeO 2 -10Nb 2 O 5 -(x)ZnO (x =0-15 mol%) have been prepared by melt-quenching method and the effect of reduction of TeO 2 with simultaneous increase in ZnO on elastic properties was studied. Ultrasonic longitudinal and shear velocity showed initial decrease of 3.52% and 2.37%, respectively, at x = 5 mol%. For x N 5 mol%, longitudinal velocity showed weak recovery but shear velocity showed steady recovery with ZnO and recorded 0.95% increase in value at x =15 mol% compared to x =0 sample. Shear and Young's moduli recorded similar drop at x = 5 mol% followed by strong recovery at x N 5 mol%, while longitudinal and Bulk modulus showed weak and no recovery, respectively, with x. Infrared (IR) absorption spectra showed increase in intensity of NbO 6 -assigned peak accompanied by increase in intensity of ZnO 4 tetrahedra and TeO 4 trigonal bipyramid (tbp) assigned peaks indicating formation of both non-bridging oxygen, NBO and bridging oxygen, BO, respectively, with addition of ZnO. The initial drop in ultrasonic velocity and related elastic moduli observed at x = 5 mol% indicates weakening of network rigidity of the glass system due to structural modification as a direct effect of TeO 2 reduction and existence of NBO. However, further replacement of TeO 2 by ZnO at x N 5 mol% contributed to increase in BO causing rigidity of the glass network to improve. In addition, hardness, H, was observed to increase with ZnO indicating increase in connectivity of the glass network while Poisson's ratio, σ, decreased indicating increase in cross-link density of the glass system. The combined results of ultrasonic velocity and IR absorption spectra suggest that the role of TeO 2 is very critical in the ternary glass system as, although ZnO addition showed improved rigidity due to recovery of shear modulus, the weakening of longitudinal and Bulk moduli indicates ZnO is not fully effective as glass former in place of TeO 2 .

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A series of glasses [(TeO 2 ) x (B 2 O 3 ) 1−x ] 1−y [Ag 2 O] y with x=70 and y=10, 15, 20, 25 and 30 mol% were synthesised by rapid quenching. Longitudinal and shear ultrasonic velocity were measured at room temperature and at 5 MHz frequency. Elastic properties, Poisson's ratio, microhardness, softening temperature and Debye temperature have been calculated from the measured density and ultrasonic velocity at room temperature. The experimental results indicate that the elastic constants depend upon the composition of the glasses and the role of the Ag 2 O inside the glass network is discussed. Estimated parameters based on Makishima-Mackenzie theory and bond compression model were calculated in order to analyse the experimental elastic moduli. Comparison between the experimental elastic moduli data obtained in the study and the calculated theoretically by the mentioned above models has been discussed.