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Sedimentological insights underpin many of the important recent advances in understanding of Earth system behaviour in the Neoproterozoic Era. This article reviews three main areas: (i) chemical proxies and their preservation, with emphasis on carbonate facies; (ii) glacial and post-glacial facies, including their age constraints; (iii) sedimentary evidence for biotic innovations and responses. Chemostratigraphy plays an important role in ordering Neoproterozoic events and defining disturbances to the carbon cycle. There is increasing attention being paid to assessing the role of diagenetic origination or modification of chemostratigraphic signals. Alongside this, new criteria for identifying primary dolomite and precursor metastable phases such as ikaite have been developed. In respect of oxygenation, geochemical proxies substantiate the concept of a Neoproterozoic Oxygenation Event as a very gradual transition, the ocean being at any one time a heterogeneous assemblage of ferruginous, sulphidic and oxic conditions, with some evidence of increasing deep-sea oxidation through the Ediacaran Period. Techniques such as Fe-speciation need to be supplemented with proxies sensitive to suboxic conditions. More generally, it is predicted that petrographically constrained microanalytical studies will also become more important in reconstructing palaeoenvironmental conditions. The global distribution of Neoproterozoic glacial deposits combined with palaeomagnetic evidence supports the concept of panglaciations in which ice sheets reached sea-level in the tropics. Advances in radiometric dating have demonstrated the synchronous onset of global (Sturtian) glaciation at 717 Ma and the demise of a second (Marinoan) glaciation at 635 Ma, and plausibly indicate long durations for each (55 Myr for Sturtian and 5 to 15 Myr for Marinoan). However, a compilation of radiometric dates indicates ambiguities indicating the need for further improvements to the radiometric and Sr-isotope database to understand events within the Sturtian time frame, the timing of onset of Marinoan glaciations, and the age and synchroneity of individual negative d 13 C anomalies. Sturtian deposits are typically thick, rift-related successions containing a range of environments influenced or dominated by dynamic glaciers, as well as ice-free marine intervals. Marinoan glacial deposits, by contrast, tend to be thin and continental. During the latter interval, oxygen isotope systematics of sulphate demonstrate that atmospheric CO 2 was high, as predicted by Snowball Earth theory, and that sedimentation was influenced by orbital forcing. The Sturtian record, by comparison, needs to be searched for evidence of cold-climate hiatuses on the one hand and orbital forcing on the other. Cap carbonate formation appears to have coincided with rising sea-levels following panglaciations. Snowball theory considers that they formed rapidly in the postglacial greenhouse, but an alternative (2016) 63, 253-306 doi: 10.1111/sed.12261 STATE OF THE SCIENCE model o...

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Natural fractures control primary fluid flow in low-matrix-permeability carbonate hydrocarbon reservoirs, making it important to understand the factors that affect natural fracture distributions and networks. Away from the influence of folds and faults, stratigraphic controls are accepted to be the major control on fracture networks. The influence of carbonate nodular chert rhythmite successions on natural fracture networks is investigated here using a Discrete Element Modelling (DEM) technique that draws on outcrop observations of naturally fractured carbonates in the Eocene Thebes Formation, exposed in the west central Sinai of Egypt, that also form reservoir rocks in the subsurface. Stratally-bound chert nodules below bedding surfaces create lateral heterogeneities that vary over short distances. The resulting distribution of physical properties (differing stiffnesses) caused by chert rhythmites is shown to generate extra complexity in natural fracture networks in addition to that caused by bed thickness and lithological physical properties. Chert rhythmite successions need to be considered as a distinct type of carbonate fractured reservoir. Stratigraphic rules for predicting the distribution, lengths and spacing of natural fractures, and quantitative fracture indices (P11, P21, P22 and fractal dimension) are generated from the DEM outcomes. In a less-stiff carbonate medium, the presence of chert nodules reduces fracture intensity at chert horizons, and fractures per unit area are higher in chert-free vertical corridors. In a stiff carbonate medium, chert has little influence on fracture development. In a peritidal cyclic succession with constant layer thicknesses, the presence of chert in less-stiff carbonate horizons results in a reduction in fracture intensity. When chert is introduced in a subtidal cyclic sequence with constant layer thicknesses, it has little effect on fracture distribution. The study has widespread significance for characterizing naturally fractured reservoirs containing carbonate nodular chert rhythmites.

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The geological paradox of at least two Neoproterozoic glacial intervals at tropical latitudes intercalated within carbonates remains an unsolved puzzle. Several conceptual models have been proposed to explain these apparent rapid swings between climatic extremes and the associated isotopic changes in sea-water chemistry. In Oman, post-glacial transgressive sedimentary successions represent important hydrocarbon source rocks. Source rock characteristics of Neoproterozoic post-glacial successions in other parts of the world (even if not directly correlatable) are, therefore, of special economic interest.This paper concentrates on the Ghaub Formation diamictite interval in northern Namibia and the major environmental change in the aftermath of the assumed glaciation. The relationship of the post-glacial sediments with the underlying different types of cap carbonate and diamictite successions is discussed, and a model of the succession of events is presented. The palaeotopography, caused mostly by ongoing tectonic activity including uplift on the scale of thousands of metres, strongly influenced the petroleum system created and played an important role for the hydrocarbon prospectivity of this post-glacial succession. Tectonic activity on the shelf of the southern margin of the Congo Craton was repeated, and different sub-basins were created before, during and after the Ghaub glaciation. The newly formed relief was flooded, and the different sub-basins were affected by restricted circulation for quite some time. This general scenario bears many similarities to the late Ordovician-early Silurian petroleum system, also formed during post-glacial sea-level rise.

Naturally fractured reservoirs, within which porosity, permeability pathways and/or impermeable barriers formed by the fracture network interact with those of the host rock matrix to influence fluid flow and storage, can occur in sedimentary, igneous and metamorphic rocks. These reservoirs constitute a substantial percentage of remaining hydrocarbon resources; they create exploration targets in otherwise impermeable rocks, including under-explored crystalline basement, and they can be used as geological stores for anthropogenic carbon dioxide. Their complex fluid flow behaviour during production has traditionally proved difficult to predict, causing a large degree of uncertainty in reservoir development. The applied study of naturally fractured reservoirs seeks to constrain this uncertainty and maximize production by developing new understanding, and is necessarily a broad, integrated, interdisciplinary topic. Some of the methods, challenges and advances in characterizing the interplay of rock matrix and fracture networks relevant to fluid flow and hydrocarbon recovery are reviewed and discussed via the contributions in this volume.Global estimates of conventional hydrocarbon resources are typically subdivided based on lithological reservoir types for example, carbonate or siliciclastic (e.g. Roehl & Choquette 1985). However, many of these sedimentary rock reservoirs may contain fractures to a greater or lesser degree. The recent boom of unconventional reservoirs highlights once again the key role that natural fractures can play in helping production of fluids. It also requires an improved understanding of the geology and physics of natural fracture networks to meet public expectations regarding safety issues. Moreover, fracture networks can be present in otherwise impermeable crystalline basement rocks (e.g. Sanders et al. 2003;Murray & Montgomery 2012;Slightam 2012) and igneous intrusions (e.g. Gudmundsson & Løtveit 2012), also allowing these rocks to form potential fractured reservoirs. Historically, fractured crystalline basement rocks have been under-explored as potential hydrocarbon reservoirs. Naturally fractured reservoirs constitute a substantial percentage of remaining hydrocarbon resources. Naturally fractured reservoirsA reservoir fracture is a general term used to describe a 'naturally occurring macroscopic planar discontinuity in rock due to deformation, or physical diagenesis' (Nelson 2001). Reservoir fractures encompass both extensional ( joints) and shear (faults) structures. Fractures formed by brittle tectonic deformation are the most common focus for studies of naturally fractured reservoirs. However, reservoir fractures may also include structures that formed by desiccation (e.g. shrinkage cracks) and syneresis (e.g. chickenwire texture) in sediments, and structures that formed by thermal , as used here. Naturally fractured reservoirs are generally defined as such when the fracture network has a significant influence on fluid flow in the reservoir such that: (1) the fracture networ...