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The cycloaddition of carbon dioxide into value-added chemicals is of great significance to reduce the carbon-emission. Herein, a Mn-based coordination polymer [(CH3)2NH2]2n[Mn3(L)2]n·nDMF·0.5nH2O (JLNU-104) has been constructed by the solvothermal reaction...

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A novel anionic Cd-MOF ([(CH3)2NH2]n[Cd(HL)DMF]n·2nH2O·nDMF, H4L = 1,2,4,5-tetrakis[(4-carboxy)phenoxymethyl]benzene) was synthesized for the first time. It, as precursor, was utilized to achieve Fe@Cd-MOF crystals via the substitution of Fe3+ ions due...

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