The structure, morphology and thermal properties of biobased and biodegradable poly(butylene succinate-ran-butylene azelate) random copolyesters with a wide composition range were studied. These PBS-ran-PBAz copolymers can crystallize in the entire composition range despite being random, displaying a eutectic point when their melting point is plotted as a function of composition. Wide Angle Xray Scattering (WAXS) studies confirmed isodimorphic behavior where PBS-rich copolymers crystallize with PBS type unit cells with some PBAz repeating units inclusions and vice versa for PBAz-rich copolymers. Away from eutectic compositions the copolymers exhibit only one crystalline phase (PBS-rich or PBAzrich crystalline phases) while at the eutectic point both phases can crystallize. The only double crystalline copolymer amongst those prepared had a composition close to the eutectic point of 45 mol% PBS (and 55 mol% PBAz). The crystallization of the two phases occurred in the same temperature range upon cooling from the melt at 10ºC/min in a DSC (i.e., coincident crystallization). Self-nucleation (SN) studies of the PBS-rich phase were performed. After SN, the separate crystallization of each phase was clearly observed during cooling from the self-nucleation temperature (i.e., PBS and PBAz-rich phases). Small Angle X-ray Scattering (SAXS) experiments were performed for the first time for this type of isodimorphic copolymers. The results show that the lamellar long period is a strong function of composition. While limited inclusions of PBAz units within the crystal lattice only cause a slight expansion of the PBS component unit cell, the increase of comonomer content produces an unexpected synergistic increase in long periods and lamellar thickness values. In the case of the only double crystalline copolymer examined, the PBS-rich phase forms space filling spherulites (observed by Polarized Light Optical Microscopy, PLOM) at higher temperatures that template the superstructural morphology of the copolymer. These PBS-rich phase spherulites contain radial lamellar stacks whose long period was determined by SAXS. Upon further cooling, the PBAz-rich phase crystallizes in the intra-spherulitic amorphous regions with newly form lamellae that have their own distinct long period according to SAXS results. AFM observations of the PBS-rich crystalline lamellae confirmed the lamellar thickness and long spacings determined by SAXS. A schematic morphological model of the mixed spherulites produced by this double crystalline diblock copolymer is proposed based on the experimental evidences collected by SAXS, PLOM and AFM.

The standard model of particle physics currently provides our best description of fundamental particles and their interactions. The theory predicts that the different charged leptons, the electron, muon and tau, have identical electroweak interaction strengths. Previous measurements have shown that a wide range of particle decays are consistent with this principle of lepton universality. This article presents evidence for the breaking of lepton universality in beauty-quark decays, with a significance of 3.1 standard deviations, based on proton–proton collision data collected with the LHCb detector at CERN’s Large Hadron Collider. The measurements are of processes in which a beauty meson transforms into a strange meson with the emission of either an electron and a positron, or a muon and an antimuon. If confirmed by future measurements, this violation of lepton universality would imply physics beyond the standard model, such as a new fundamental interaction between quarks and leptons.

Poly(lactic acid) (PLA) is one of the most promising alternatives for petrochemical-based plastics. Crystallization mediation provides the simplest and most practical approach for enhancing the properties of PLA. Here, recent advances in understanding the relationship between crystalline structure and properties of PLA are summarized. Methods for manipulating crystallization towards high-performance PLA materials are introduced.

We determined three-dimensional P and S wave velocities and P wave azimuthal anisotropic tomography of the Northwest Pacific subduction zones by inverting 1,225,086 P wave and 335,117 S wave arrival times from 13,413 earthquakes. Our results show some differences between P and S wave images for the stagnant Pacific slab in the mantle transition zone (MTZ) beneath Northeast China. The stagnant slab looks thicker in the P wave image than that in the S wave image, which may reflects the effects of both hydration and lower temperature in the MTZ, though differences in the resolution of P and S wave tomography may also have some effects. The Changbai intraplate volcanism is caused by hot and wet upwelling in the big mantle wedge above the stagnant Pacific slab. Our P wave anisotropy tomography shows that the fast velocity direction (FVD) in the subducting Philippine Sea plate beneath the Ryukyu arc is NE-SW (trench parallel), which is consistent with the spreading direction of the West Philippine Basin during its initial opening stage, suggesting that it may reflect the fossil anisotropy. A striking variation of the FVD with depth is revealed in the subducting Pacific slab beneath the Northeast Japan arc, which may be caused by slab dehydration that changed elastic properties of the slab with depth. The FVD in the mantle wedge beneath the Northeast Japan and Ryukyu arcs is trench normal, which reflects subduction-induced convection. Beneath the Kuril and Izu-Bonin arcs where oblique subduction occurs, the FVD in the mantle wedge is nearly normal to the moving direction of the downgoing Pacific plate, suggesting that the oblique subduction together with the complex slab morphology have disturbed the mantle flow.

Lepton scattering is an established ideal tool for studying inner structure of small particles such as nucleons as well as nuclei. As a future high energy nuclear physics project, an Electron-ion collider in China (EicC) has been proposed. It will be constructed based on an upgraded heavy-ion accelerator, High Intensity heavy-ion Accelerator Facility (HIAF) which is currently under construction, together with a new electron ring. The proposed collider will provide highly polarized electrons (with a polarization of ∼80%) and protons (with a polarization of ∼70%) with variable center of mass energies from 15 to 20 GeV and the luminosity of (2–3) × 1033 cm−2 · s−1. Polarized deuterons and Helium-3, as well as unpolarized ion beams from Carbon to Uranium, will be also available at the EicC.The main foci of the EicC will be precision measurements of the structure of the nucleon in the sea quark region, including 3D tomography of nucleon; the partonic structure of nuclei and the parton interaction with the nuclear environment; the exotic states, especially those with heavy flavor quark contents. In addition, issues fundamental to understanding the origin of mass could be addressed by measurements of heavy quarkonia near-threshold production at the EicC. In order to achieve the above-mentioned physics goals, a hermetical detector system will be constructed with cutting-edge technologies.This document is the result of collective contributions and valuable inputs from experts across the globe. The EicC physics program complements the ongoing scientific programs at the Jefferson Laboratory and the future EIC project in the United States. The success of this project will also advance both nuclear and particle physics as well as accelerator and detector technology in China.

A reversibly cross‐linked epoxy resin with efficient reprocessing and intrinsic self‐healing was prepared from a diamine Diels‐Alder (DA) adduct cross‐linker and a commercial epoxy oligomer. The newly synthesized diamine cross‐linker, comprising a DA adduct of furan and maleimide moieties, can cure epoxy monomer/oligomer with thermal reversibility. The reversible transition between cross‐linked state and linear architecture endows the cured epoxy with rapid recyclability and repeated healability. The reversibly cross‐linked epoxy fundamentally behaves as typical thermosets at ambient conditions yet can be fast reprocessed at elevated temperature like thermoplastics. As a potential reversible adhesive, the epoxy polymer with adhesive strength values about 3 MPa showed full recovery after repeated fracture‐thermal healing processes. The methodology explored in this contribution provides new insights in modification of conventional engineering plastics as functional materials. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 2094–2103

Over 12 years of continuous monitoring of Changbaishan volcano in the border region of China and North Korea by means of volcanic seismicity, ground deformation, and volcanic gas geochemistry yields new evidence for magmatic unrest of the volcano between 2002 and 2006. In this so‐called “active period,” the frequency of volcanic earthquakes increased by about 2 orders of magnitude compared to that of the background “inactive periods.” The active period was also accompanied by ground inflation, high values of CO2, He, H2, and high ratios of N2/O2 and 3He/4He in volcanic gases released from three hot springs near the caldera rim. The monitoring evidence implies pressurization of the magma chamber, possibly caused by incremental magma recharge. The ground deformation data from both GPS and precise leveling are modeled to suggest the corresponding deformation source is at 2–60 km depth beneath the volcano's summit, where earthquake swarms were detected in 2002 and 2003. Our findings suggest that the magma chamber beneath Changbaishan volcano has awakened and resumed activity after remaining dormant since AD 1903. There is an urgent need to keep close watch on this active and very hazardous volcano in northeast China.

The epitaxy forced crystallization behavior of thin film olefin block copolymer (OBC) samples was investigated in the presence of benzoic acid (BA). The investigated OBC samples show apparent phase separation in the melt. However, their dissimilar comonomer difference between hard and soft segments (ΔC8) and block lengths results in different segregation strength, which controls their crystallization behavior. Independent of the crystallization conditions, for both OBCs the BA substrate induces highly oriented and epitaxially grown lamellar crystals. In case of the weakly melt segregated OBC, crystallization always breakout the melt separated phase domains, and crystals are homogeneously distributed in the entire sample. For strongly melt segregated OBC, on the other hand, phase separation is maintained when quenching the samples, and only isolated crystalline domains are formed. However, subsequent annealing of quenched samples, slow cooling from the melt, or isothermal crystallization at low supercoolings on the BA substrate forces crystals breakout the initial confinement. Such crystallization experiments help us better understanding the interplay between molecular architecture, segregation strength, and controlled crystallization conditions on the organization of OBCs.