Biochar is a carbon-rich solid material derived from the pyrolysis of agricultural and forest residual biomass. Previous studies have shown that biochar is suitable as an adsorbent for soil contaminants such as heavy metals and consequently reduces their bioavailability. However, the long-term effect of different biochars on metal extractability or soil health has not been assessed. Therefore, a 1-year incubation experiment was carried out to investigate the effect of biochar produced from bamboo and rice straw (at temperatures ≥500 °C) on the heavy metal (cadmium (Cd), copper (Cu), lead (Pb), and zinc (Zn)) extractability and enzyme activity (urease, catalase, and acid phosphatase) in a contaminated sandy loam paddy soil. Three rates (0, 1, and 5%) and two mesh sizes (<0.25 and <1 mm) of biochar applications were investigated. After incubation, the physicochemical properties, extractable heavy metals, available phosphorus, and enzyme activity of soil samples were analyzed. The results demonstrated that rice straw biochar significantly (P < 0.05) increased the pH, electrical conductivity, and cation exchange capacity of the soil, especially at the 5% application rate. Both bamboo and rice straw biochar significantly (P < 0.05) decreased the concentration of CaCl2-extractable heavy metals as biochar application rate increased. The heavy metal extractability was significantly (P < 0.01) correlated with pH, water-soluble organic carbon, and available phosphorus in soil. The 5% application rate of fine rice straw biochar resulted in the greatest reductions of extractable Cu and Zn, 97.3 and 62.2%, respectively. Both bamboo and rice straw biochar were more effective at decreasing extractable Cu and Pb than removing extractable Cd and Zn from the soil. Urease activity increased by 143 and 107% after the addition of 5% coarse and fine rice straw biochars, respectively. Both bamboo and rice straw biochars significantly (P < 0.05) increased catalase activity but had no significant impact on acid phosphatase activity. In conclusion, the rice straw biochar had greater potential as an amendment for reducing the bioavailability of heavy metals in soil than that of the bamboo biochar. The impact of biochar treatment on heavy metal extractability and enzyme activity varied with the biochar type, application rate, and particle size.
Abstract. Evapotranspiration (ET) from the wetland of the Yellow River Delta (YRD) is one of the important components in the water cycle, which represents the water consumption by the plants and evaporation from the water and the non-vegetated surfaces. Reliable estimates of the total evapotranspiration from the wetland is useful information both for understanding the hydrological process and for water management to protect this natural environment. Due to the heterogeneity of the vegetation types and canopy density and of soil water content over the wetland (specifically over the natural reserve areas), it is difficult to estimate the regional evapotranspiration extrapolating measurements or calculations usually done locally for a specific land cover type. Remote sensing can provide observations of land surface conditions with high spatial and temporal resolution and coverage. In this study, a model based on the Energy Balance method was used to calculate daily evapotranspiration (ET) using instantaneous observations of land surface reflectance and temperature from MODIS when the data were available on clouds-free days. A time series analysis algorithm was then applied to generate a time series of daily ET over a year period by filling the gaps in the observation series due to clouds. A detailed vegetation classification map was used to help identifying areas of various wetland vegetation types in the YRD wetland. Such information was also used to improve the parameterizations in the energy balance model to improve the accuracy of ET estimates. This study showed that spatial variation of ET was significant over the same vegetation class at a given time and over different vegetation types in different seasons in the YRD wetland.
We report on silver-gold core-shell nanostructures that contain Methylene Blue (MB) at the gold-silver interface. They can be used as reporter molecules in surfaceenhanced Raman scattering (SERS) labels. The labels are stable and have strong SERS activity. TEM imaging revealed that these nanoparticles display bright and dark stripe structures. In addition, these labels can act as probes that can be detected and imaged through the specific Raman signatures of the reporters. We show that such SERS probes can identify cellular structures due to enhanced Raman spectra of intrinsic cellular molecules measured in the local optical fields of the core-shell nanostructures. They also provide structural information on the cellular environment as demonstrated for these nanoparticles as new SERS-active and biocompatible substrates for imaging of live cells.
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