Abstract. 1 The article presents results of thermodynamic modeling of Fe-Si-Al complex containing alloy of the silica clay (77.8 % Al 2 O 3 , 11.6 % Al 2 O 3 ). The modeling is based on the principle of minimum Gibbs energy and fulfilled by means of software complex HSC-5.1. It was found that the joint reduction of silicon and aluminum from an amorphous SiO 2 and Al 2 O 3 is characterized by higher thermodynamic probability than from a mixture of a crystalline SiO 2 and Al 2 O 3 . At the silicon reduction there is the undesirable formation of a gaseous SiO; the transition degree of silicon in SiO can be reduced by means of decrease in temperature and increase in carbon content.
The article contains the research results of obtaining a ferroalloy from a carbon ferrochrome dust containing 30,2% of Сr2O3, 23.4% of SiO2, 32.7% of MgO, 5.0% of FeO, 1.6% of CaO, 4.5%of Al2O3, 2.3%of C, and 0.3 %-others. The studies were carried out by a thermodynamic modeling method using the HSC-5.1 software package (Outokumpy) based on the principle of the Gibbs energy minimum, the Box-Hunter rototable planning technique and electric melting of the dust in an arc furnace. It was found that the interaction of the dust with carbon under equilibrium conditions and in the presence of iron leads to formation of Cr4C(T>10000C),Cr3C2, Cr7C3,Cr (T>11000C), FeSi (T>13000C), SiC (T>14000C), SiOg and Si(T>15000C). In the temperature range of 1745-19000C and in the presence of 18-34% of carbon and 8% of iron of the dust mass, the resulting ferroalloy contained 18.5-25.2% of Si and 46.8-49.4% of Cr (in this case the silicon extraction degree into the alloy was 60.0-64.4%, the chromium one–99.8%). When the electrosmelting the granulated dust together with coke and steel shavings, the chromium extraction degree into the alloy was 98-99%, the silicon one–53-57%; the obtained ferroalloys containing 18.3-21.9% of silicon and 45.6-53.6%of chromium meet the requirements to FeCrSi23-grade ferrosilicochromium.
E d i t o r i a l b o a r d: ABSAMETOV Malis Kudysovich, (deputy editor-in-chief), doctor of geological and mineralogical sciences, professor, academician of NAS RK, director of the Akhmedsafin Institute of hydrogeology and hydrophysics (Almaty, Kazakhstan) H = 2 ZHOLTAEV Geroy Zholtaevich, (deputy editor-in-chief), doctor of geological and mineralogical sciences, professor, director of the institute of geological sciences named after K.I. Satpayev (Almaty, Kazakhstan) Н=2 SNOW Daniel, Ph.D, associate professor, director of the labotatory of water sciences, Nebraska University (Nebraska, USA) H = 32 Zeltman Reymar, Ph.D, head of research department in petrology and mineral deposits in the Earth sciences section of the museum of natural history (London, England) H = 37 PANFILOV Mikhail Borisovich, doctor of technical sciences, professor at the Nancy University (Nancy, France) Н=15 SHEN Ping, Ph.D, deputy director of the Committee for Mining geology of the China geological Society, Fellow of the American association of economic geologists (Beijing, China) H = 25 FISCHER Axel, Ph.D, associate professor, Dresden University of technology (Dresden, Germany) H = 6 KONTOROVICH Aleksey Emilievich, doctor of geological and mineralogical sciences, professor, academician of RAS, Trofimuk Institute of petroleum geology and geophysics SB RAS (Novosibirsk, Russia) H = 19 ABSADYKOV Bakhyt Narikbaevich, doctor of technical sciences, professor, corresponding member of NAS RK, Bekturov Institute of chemical sciences (Almaty, Kazakhstan) H = 5 AGABEKOV Vladimir Enokovich, doctor of chemistry, academician of NAS of Belarus, honorary director of the Institute of chemistry of new materials (Minsk, Belarus) H = 13 KATALIN Stephan, Ph.D, associate professor, Technical university (Dresden, Berlin) H = 20 SEITMURATOVA Eleonora Yusupovna, doctor of geological and mineralogical sciences, professor, corresponding member of NAS RK, head of the laboratory of the Institute of geological sciences named after K.I. Satpayev (Almaty, Kazakhstan) Н=11 SAGINTAYEV Zhanay, Ph.D, associate professor, Nazarbayev University (Nursultan, Kazakhstan) H = 11 FRATTINI Paolo, Ph.D, associate professor, university of Milano-Bicocca (Milan, Italy) H = 28 News of the National Academy of Sciences of the Republic of Kazakhstan. Series of geology and technology sciences.
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