In this study, polyethersulfone (PES) and polyvinylidene fluoride (PVDF) microfiltration membranes containing polyvinylpyrrolidone (PVP) with and without support layers of 130 and 150 μm thickness are manufactured using the phase inversion method and then experimentally characterised. For the characterisation of membranes, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and pore size analysis are performed, the contact angle and water content of membranes are measured and the tensile test is applied to membranes without support layers. Using the results obtained from the tensile tests, the mechanical properties of the halloysite nanotube (HNT) and nano-silicon dioxide (nano SiO2) reinforced nanocomposite membranes are approximately determined by the Mori–Tanaka homogenisation method without applying any further mechanical tests. Then, plain polymeric and PES and PVDF based nanocomposite membranes are modelled using the finite element method to determine the effect of the geometry of the membrane on the mechanical behaviour for fifteen different geometries. The modelled membranes compared in terms of three different criteria: equivalent stress (von Mises), displacement, and in-plane principal strain. Based on the data obtained from the characterisation part of the study and the numerical analysis, the membrane with the best performance is determined. The most appropriate shape and material for a membrane for water treatment is specified as a 1% HNT doped PVDF based elliptical membrane.
To investigate the effect of polyvinylpyrrolidone (PVP) addition and consequently porosity, two different sets of membranes are manufactured, since PVP is a widely used poring agent which has an impact on the mechanical properties of the membrane material. The first set (PAN 1) includes polyacrylonitrile (PAN) and the necessary solvent while the second set (PAN 2) is made of PAN and PVP. These membranes are put through several characterisation processes including tensile testing. The obtained data are used to model the static behaviour of the membranes with different geometries but similar loading and boundary conditions that represent their operating conditions. This modelling process is undertaken by using the finite element method. The main idea is to investigate how geometry affects the load-carrying capacity of the membranes. Alongside membrane modelling, their materials are modelled with representative elements with hexagonal and rectangular pore arrays (RE) to understand the impact of porosity on the mechanical properties. Exploring the results, the best geometry is found as the elliptic membrane with the aspect ratio 4 and the better RE as the hexagonal array which can predict the elastic properties with an approximate error of 12%.
In this study, polyethersulfone (PES) ultrafiltration membrane surface was modified with nano-sized zinc oxide (nZnO) and silver (nAg) to improve the membrane filterability of the mixed liquor and used to treat fruit-juice industry wastewater in a submerged membrane bioreactor (MBR). The nAg was synthesized using three different methods. In the first method, named as nAg-M1, PES membrane was placed on the membrane module and nAg solution was passed through the membrane for 24 h at 25 ± 1 °C. In the second method, named as nAg-M2, PES membrane was placed in a glass container and it was shaken for 24 h at 150 rpm at 25 ± 1 °C. In the third method, named as nAg-M3, Ag nanoparticles were loaded onto PES membrane in L-ascorbic acid solution (0.1 mol/L) at pH 2 for 24 h at 150 rpm at 25 ± 1 °C. For the preparation of nZnO coated membrane, nZnO nanoparticles solution was passed through the membrane for 24 h at 25 ± 1 °C. Anti-fouling performance of pristine and coated membranes was examined using the submerged MBR. The results showed that nZnO and nAg-M3 membranes showed lower flux decline compared with pristine membrane. Moreover, pristine and coated PES membranes were characterized using a permeation test, contact angle goniometer, and scanning electron microscopy.
In this study, neat polyacrylonitrile (PAN) and fumed silica (FS)-doped PAN membranes (0.1, 0.5 and 1 wt% doped PAN/FS) are prepared using the phase inversion method and are characterised extensively. According to the Fourier Transform Infrared (FTIR) spectroscopy analysis, the addition of FS to the neat PAN membrane and the added amount changed the stresses in the membrane structure. The Scanning Electron Microscope (SEM) results show that the addition of FS increased the porosity of the membrane. The water content of all fabricated membranes varied between 50% and 88.8%, their porosity ranged between 62.1% and 90%, and the average pore size ranged between 20.1 and 21.8 nm. While the neat PAN membrane’s pure water flux is 299.8 L/m2 h, it increased by 26% with the addition of 0.5 wt% FS. Furthermore, thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) techniques are used to investigate the membranes’ thermal properties. Finally, the mechanical characterisation of manufactured membranes is performed experimentally with tensile testing under dry and wet conditions. To be able to provide further explanation to the explored mechanics of the membranes, numerical methods, namely the finite element method and Mori–Tanaka mean-field homogenisation are performed. The mechanical characterisation results show that FS reinforcement increases the membrane rigidity and wet membranes exhibit more compliant behaviour compared to dry membranes.
In this work, a series of polyetherimide (PEI) flat sheet membranes were produced with different concentrations of polyvinylpyrrolidone (PVP) addition via the phase inversion method. The effects of additions on membrane morphology and performance were investigated. Synthesized membrane had the properties of ultrafiltration membrane. Although PEI is not widely used for water treatment, in this study, the ferrous iron removal rate was investigated and good results were obtained. Through the membrane production experiments, the PEI content was 22 wt%. PVP was added as a pore-forming agent with concentrations of 2, 4 and 8 wt%. N-methyl-2-pyrrolidone (NMP) was used as solvent. Distilled water was used for the coagulation bath. After production, all membranes were characterized by using contact angle, permeability, porosity, and scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT/IR) analyses. With the increasing doses of PVP addition, the permeability of the PEI membranes produced in this study increased, while porosity results were changeable. The permeability was 23 L/m2h bar for the membrane with 2 wt% PVP content, while the permeability for the membrane with 8 wt% PVP content was 32 L/m2h bar. Contact angles increased with PVP addition to PEI membranes. With the increasing PVP concentration, the finger-like pores and the pores located in the sub-layer expanded.
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