Enzyme-induced carbonate precipitation (EICP) is an emerging biogeotechnical technique that uses free urease to improve soil. Despite its advantages of eliminating complex microbial cultures and reducing reaction byproducts, its efficiency is considered lower than that of microbial induced calcite precipitation (MICP) due to the lack of nucleation sites that induce calcium carbonate deposition. To enhance the strengthening efficiency of EICP for fine-grained soils, an improved EICP method that involves adding an appropriate mass concentration of organic materials (skim milk powder, glutinous rice powder, and brown sugar) into urease solution was proposed and applied to reinforce silt in the Yellow River flood area of China. The preferred concentration and ratio of cementation solution and the optimum concentration of each of the organic materials were determined. Then, the reinforcement effect of the improved EICP at the optimum concentration was compared with the control group, and the reinforcement mechanism for this method was discussed. The results show that after the organic material inclusions, soil strength can be enhanced by 33% compared with EICP-treated soil and is nearly four times higher than that of untreated soil. The superiority of this method over traditional EICP and MICP mainly stems from its ability to provide templates and nucleation sites for calcium carbonate deposition and to improve the size, morphology, and structure of calcium carbonate crystals.
Enzyme-induced calcium carbonate precipitation (EICP) technology can improve the strength of treated soil. But it also leads to remarkable brittleness of the soil. This study used polyvinyl alcohol (PVA) fiber combined with EICP to solidify sand. Through the unconfined compressive strength (UCS) test, the effect of PVA fiber incorporation on the mechanical properties of EICP-solidified sand was investigated; the distribution of CaCO3 in the sample and the microstructure of fiber-reinforced EICP-treated sand were explored through the calcium carbonate content (CCC) test and microscopic experiment. Compared with the sand treated by EICP, the strength and stiffness of the sand reinforced by the fiber combined with EICP were greatly improved, and the ductility was also improved to a certain extent. However, the increase of CCC was extremely weak, and the inhomogeneity of CaCO3 distribution was enlarged; the influence of fiber length on the UCS and CCC of the treated sand was greater than that of the fiber content. The improvement of EICP-solidified sand by PVA fiber was mainly due to the formation of a “fiber–CaCO3–sand” spatial structure system through fiber bridging, not the increase of CCC.
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