The Ga 2 O 3 anode has great potential due to its self-healing and high theoretical capacity in lithium-ion batteries. Like anodes with other transition metal oxides, the Ga 2 O 3 anode has the problems of structural change and low electrical conductivity. The electrochemical performance of the Ga 2 O 3 anode still needs to be improved. In this work, we synthesized a Ga 2 O 3 quantum dots@N-doped carbon (Ga 2 O 3 -QD@NC) composite by hydrothermal reaction with a carbon source of dopamine hydrochloride, in which Ga 2 O 3 quantum dots were dispersed in the interior of the amorphous carbon. Such a special structure is conducive to the high-speed migration of lithium ions and electrons and effectively inhibits volume expansion and agglomeration. Smaller and more uniform quantum dots facilitate efficient repair of the structure. Due to these advantages, the Ga 2 O 3 -QD@NC electrode has great electrochemical performance. The Ga 2 O 3 -QD@NC electrode has an initial discharge capacity of 1580 mAh g −1 with a high first Coulombic efficiency of 62.8% and a cycling capacity of 953 mAh g −1 under 0.1 A g −1 . It even has a capacity of 460 mAh g −1 at 1 A g −1 after 300 cycles. This strategy can provide a new direction for the Ga 2 O 3 anode in lithium-ion batteries with high capacity.
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