Surface post-treatment using ammonium halides effectively reduces large open-circuit voltage (V OC ) losses in bromine-rich wide-bandgap (WBG) perovskite solar cells (PSCs). However, the underlying mechanism still remains unclear and the device efficiency lags largely behind. Here, a facile strategy of precisely tailoring the phase purity of 2D perovskites on top of 3D WBG perovskite and realizing high device efficiency is reported. The transient absorption spectra, cross-sectional confocal photoluminescence mapping, and cross-sectional Kelvin probe force microscopy are combined to demonstrate optimal defect passivation effect and surface electric-field of pure n = 1 2D perovskites formed atop 3D WBG perovskites via low-temperature annealing. As a result, the inverted champion device with 1.77-eV perovskite absorber achieves a high V OC of 1.284 V and a power conversion efficiency (PCE) of 17.72%, delivering the smallest V OC deficit of 0.486 V among WBG PSCs with a bandgap higher than 1.75 eV. This enables one to achieve a four-terminal all-perovskite tandem solar cell with a PCE exceeding 25% by combining with a 1.25-eV low-bandgap PSC.
Based on the background of the Line F2-3 interval tunnel section of Jiujiawan in Urumqi Subway Line 1, this paper carries out the model test research on the antibreaking technology of the reducing dislocation layer in the tunnel section of the stick-slip fracture. The antibreaking effect of different locations and number of reducing dislocation layers in tunnel engineering is analyzed in this paper. The results show that when the double reducing dislocation layer, respectively, set between the surrounding rock and the primary support, and the primary support and the secondary lining, the antibreaking effect is the best. It is recommended to use this scheme for antibreaking design. The research results can provide reference for antibreaking design of traffic tunnels in active fault zones.
Adding fiber can improve the brittleness of plain concrete. Compared with plain concrete, basalt fiber-reinforced concrete has the advantages of strengthening, toughening, and crack resistance. Compared with steel fiber-reinforced concrete, basalt fiber-reinforced concrete has better construction performance. Basalt fiber concrete is a type of inorganic material with environmental protection and high mechanical properties, which has an important mechanical advantage for controlling the deformation of the soft surrounding rock tunnel. Through the indoor model test of mechanical behavior of reinforced concrete and basalt fiber-reinforced concrete lining, the bearing characteristics of basalt fiber-reinforced concrete lining was studied. The results show that, compared with reinforced concrete, the initial crack load of basalt fiber-reinforced concrete is increased by 20%; the toughness of lining structure is enhanced by adding basalt fiber, and the lining can still bear large bending moment and deformation after the initial crack appears; after the initial crack appears, the bearing characteristic curve of reinforced concrete lining rises slowly and converges rapidly; the bearing characteristic curve of basalt fiber-reinforced concrete lining rises slowly, and there is no sign of convergence when it reaches 2 times of initial crack load. For the soft surrounding rock tunnel, it is necessary to seal the rock surface as early as possible, provide support as soon as possible, and have a certain deformation capacity. Basalt fiber-reinforced concrete can better meet these needs.
Tunnels in the junction of the soft and hard rock always suffer severe damages during the strong earthquakes. This article aims to investigate the seismic effect of the combination of the buffer layer and the steel fibre reinforced concrete (SFRC) linings in tunnel seismic design. Firstly, taking the soft and hard rock junction of Fanjiazhai Tunnel as the research background, the finite difference calculation models considering the modified seismic motion, the mechanical damping, the safety factor and the seismic materials are established to study the seismic response of the tunnel crossing the soft and hard rock junction. Then, the buffer layer and the SFRC lining are applied into the soft-hard rock junction tunnel respectively, the isolation performance of the buffer layer and the strengthening effect of the SFRC lining are analyzed by using the seismic displacement, seismic acceleration and the safety factor. Finally, the combination of the buffer layer and the SFRC lining is employed in the tunnel located in soft-hard rock junction, the effectiveness and the synergistic effect of combination method are proved by numerical analysis. The research results can provide references for seismic fortification of the tunnel crossing soft and hard surrounding rock junction in meizoseismal area.
Tunnels in soft rock with high ground stress will encounter the problem of large deformation of surrounding rock. The study of new high-performance tunnel lining materials is of great significance to improve the safety of tunnel excavation in soft rock with high ground stress. In this paper, the bearing characteristics of the plain concrete, the reinforced concrete, and the steel fiber reinforced concrete lining are studied by the indoor model experiment. By extracting the displacement and stress data of typical parts of lining, the bearing characteristics of the steel fiber reinforced concrete lining are analyzed and summarized. The test results show that the initial crack load and ultimate load of the steel fiber reinforced concrete lining are significantly higher than those of the other two materials, and the crack development path is more tortuous, and the number of cracks is greater. Steel fiber can improve the bearing capacity and deformation capacity of the lining structure so that the failure mode of the lining structure changes from brittle shear failure to ductile bending failure. It is concluded that steel fiber reinforced concrete can improve the toughness of lining. Because of its excellent mechanical properties, steel fiber reinforced concrete can completely replace the conventional reinforced concrete as a new lining material for soft rock tunnel. The above research results are of great significance to the design and construction of tunnel lining in the soft surrounding rock.
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