The functionalization and performance improvement of supramolecular hydrogels are very important for their application in the wound dressing field. Inspired by the role of lignin in plant cell walls, sulfonated lignin is introduced into the supramolecular hydrogel to improve functionality, mechanical strength, and biological activity. According to the chemical structure characteristics of the sulfonated lignin and the requirements for wound dressing, a novel polymer system is designed and successfully synthesized to cooperate with the sulfonated lignin to form the supramolecular hydrogel dressings. The introduction of the sulfonated lignin can effectively improve the mechanical strength, self-healing property, antioxidant activity, and biological activity of the obtained supramolecular hydrogel dressings. In the rat wound healing model experiment, the supramolecular hydrogel dressings can maintain the moist environment on the wound surface, clean up the excretion of wound tissue, promote wound healing, and reduce the occurrence of inflammation. This supramolecular hydrogel dressing shows obvious potential for wound management and treatment by a facile and effective approach and has great promise for long-term application of wound dressings. This strategy for designing polymers according to the chemical structure characteristics of the sulfonated lignin and the application requirements has reference value for further development of biomass-based compound materials.
For the application of lignin-based materials, it is necessary to develop simple and efficient chemical modification strategies for lignin. In this work, the iodization modification strategy is selected to improve the specific surface area and graphitization degree of lignin-based carbon fibers. The introduction of an iodine atom can effectively increase the π electron cloud density of the lignin aromatic hydrocarbon structure. High π electron cloud density can effectively enhance the π−π interaction force between lignin molecules (the supramolecular bonds). The biomass precursors with this intermolecular microstructure exhibit good thermal stability and can maintain the original fibrous morphology during high-temperature treatment, which is beneficial for increasing the specific surface area of biomass-based carbon materials. Furthermore, this intermolecular microstructure also contributes to the graphitization of biomass precursor materials and reduces the spacing of graphite micro-lamellae. The obtained lignin-based carbon fibers with iodization modification exhibit a specific capacitance of 333 F/g at a current density of 1 A/g in the three-electrode tests in 6 M KOH solution. As the assembled supercapacitor, the specific capacitance of lignin-based carbon fibers reaches 87 F/g in 1 M Na 2 SO 4 solution. Compared to other modification processes for raw materials, this strategy is simple and efficient and has reference value for the synthesis of other highperformance biomass-based materials.
Hydrogel shows great potential as a flexible wearable electronic device. However, the practical application of hydrogel is still significantly limited due to the poor functional stability caused by swelling behavior, non-frost resistance caused by high water content, and obvious creep behavior under repeated external force. In this work, macromolecular lignin with a threedimensional network structure, and active functional groups are introduced into the hydrogel through the esterification grafting reaction of methacryloyl chloride. The introduction of lignin effectively improves the antiswelling, antifreezing, and creep resistance of the hydrogel sensor, while maintaining the mechanical properties (elongation at break > 350%, tensile strength > 1.5 MPa) and electrical conductivity (10 S/m). Under extreme environments, the toughness, tensile strength, and elongation at break of the hydrogel remain at more than 96%. Furthermore, the antifreezing, creep resistance, and conductivity of hydrogel sensors are not significantly affected after immersion in water for a long time (72 h). This work proposes a simple strategy to improve the antiswelling, antifreezing, and anticreep properties of hydrogels, which has guiding significance for the preparation of high-performance flexible wearable electronic materials.
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