Surface temperature is a fundamental parameter of Earth's climate. Its evolution through time is commonly reconstructed using the oxygen isotope and the clumped isotope compositions of carbonate archives. However, reaction kinetics involved in the precipitation of carbonates can introduce inaccuracies in the derived temperatures. Here, we show that dual clumped isotope analyses, i.e., simultaneous Δ 47 and Δ 48 measurements on the single carbonate phase, can identify the origin and quantify the extent of these kinetic biases. Our results verify theoretical predictions and evidence that the isotopic disequilibrium commonly observed in speleothems and scleractinian coral skeletons is inherited from the dissolved inorganic carbon pool of their parent solutions. Further, we show that dual clumped isotope thermometry can achieve reliable palaeotemperature reconstructions, devoid of kinetic bias. Analysis of a belemnite rostrum implies that it precipitated near isotopic equilibrium and confirms the warmer-than-present temperatures during the Early Cretaceous at southern high latitudes.

The Early Cretaceous (145–100 Ma) was characterized by long-term greenhouse climates, with a reduced equatorial to polar temperature gradient, although an increasingly large body of evidence suggests that this period was punctuated by episodic global “cold snaps.” Understanding climate dynamics during this high-atmospheric CO2 period of Earth’s history may have significant impact on how we understand climatic feedbacks and predict future global climate changes under an anthropogenically-driven high-pCO2 atmosphere. This study utilizes facies analysis to constrain the paleobathymetry of Lower Cretaceous glendonites—a pseudomorph after ikaite, a mineral that forms naturally at 7 °C or lower—from two paleo-high-latitude (60–70°N) sites in Svalbard, Arctic Norway, to infer global climatic changes during the Early Cretaceous. The original ikaite formed in the offshore transition zone of a shallow marine shelf at water depths of <100 m, suggesting mean annual water temperatures of ≤7 °C at these depths at 60–70°N. We correlate glendonite-bearing horizons from Lower Cretaceous successions around the globe using carbon isotope stratigraphy, in conjunction with the pre-existing biostratigraphic framework, in order to infer northern hemispheric to global climatic cooling. A distinct interval of glendonites in the Northern Hemisphere, from sites >60°N, spans the late Berriasian to earliest Barremian (at least 8.6 m.y.), significantly prolonging the duration of the previously hypothesized Valanginian cold snap (associated with the “Weissert Event”). Widespread glendonites occur again in late Aptian and extend to the early Albian, in both hemispheres, corroborating other proxy evidence for late Aptian cooling. The glendonites from Svalbard suggest that Cretaceous cold episodes were characterized with high latitude (>60°N) shallow water temperatures that are consistent with the existence of a small northern polar ice cap at this time.

A new carbon isotope record for two high-latitude sedimentary successions that span the Jurassic–Cretaceous boundary interval in the Sverdrup Basin of Arctic Canada is presented. This study, combined with other published Arctic data, shows a large negative isotopic excursion of organic carbon (δ13Corg) of 4‰ (V-PDB) and to a minimum of −30.7‰ in the probable middle Volgian Stage. This is followed by a return to less negative values of c. −27‰. A smaller positive excursion in the Valanginian Stage of c. 2‰, reaching maximum values of −24.6‰, is related to the Weissert Event. The Volgian isotopic trends are consistent with other high-latitude records but do not appear in δ13Ccarb records of Tethyan Tithonian strata. In the absence of any obvious definitive cause for the depleted δ13Corg anomaly, we suggest several possible contributing factors. The Sverdrup Basin and other Arctic areas may have experienced compositional evolution away from open-marine δ13C values during the Volgian Age due to low global or large-scale regional sea levels, and later become effectively coupled to global oceans by Valanginian time when sea level rose. A geologically sudden increase in volcanism may have caused the large negative δ13Corg values seen in the Arctic Volgian records but the lack of precise geochronological age control for the Jurassic–Cretaceous boundary precludes direct comparison with potentially coincident events, such as the Shatsky Rise. This study offers improved correlation constraints and a refined C-isotope curve for the Boreal region throughout latest Jurassic and earliest Cretaceous time.

In order to understand the climate dynamics of the Mesozoic greenhouse world, it is vital to determine paleotemperatures from higher latitudes. For the Jurassic and Cretaceous climate, there are significant discrepancies between different proxies and between proxy data and climate models. We determined paleotemperatures from Late Jurassic and Early Cretaceous belemnites using the carbonate clumped isotope paleothermometer and compared these values to temperatures derived from TEX86 and other proxies. From our analyses, we infer an average temperature of ∼25 °C for the upper part of the water column of the southern Atlantic Ocean. Our data imply that for mid- to high latitudes, climate models underestimate marine temperatures by >5 °C and, therefore, the amount of warming that would accompany an increase in atmospheric CO2 of more than 4× pre-industrial levels, as is projected for the near future.

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