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[1] Weathering of rock surfaces is often associated with a surface dissolution process. Chemical interactions occur on grain boundaries and diffusion is the controlling process. A dissolution boundary layer (rind) develops adjacent to the weathering surface. We quantify the extent of dissolution by introducing a damage variable f, f = 0 for pristine rock, and when f = f 0 the rock disintegrates. We assume that the variations of the damage variable are given by the diffusion equation. We solve two problems. The first is for the structure of the transient dissolution boundary layer prior to surface disintegration. We find an incubation time t i before active weathering (disintegration) begins. The second is the solution for steady state weathering with a constant weathering velocity v w . Our results are entirely consistent with weathering studies on Carrera marble gravestones in the United Kingdom.

Uplift of the Tian Shan range modified regional climate during Cenozoic aridification in Central Asia. This study presents facies analyses and Neogene oxygen and carbon isotopic records from magnetostratigraphically dated terrestrial sedimentary sections on the southern side of the intermontane Issyk-Kul basin in the Kyrgyz Tian Shan and 26 Al/ 10 Be isochron burial ages from the southern and eastern sides of the basin. The δ 18 O and δ 13 C data show a positive ca. 2‰ shift in values between ca. 8 and 7 Ma and a change from a negative to a positive trend. This change is attributed to the upwind growth of the Kyrgyz, Kungey and Trans Ili (Zaili) ranges, which diverted the westerlies, thereby changing the Issyk-Kul basin from a windward to a leeward position, enhancing aridification and establishing the modern-day spring and summer precipitation regime within the basin. Two 4 to 5 Ma 26 Al/ 10 Be isochron burial ages constrain the onset of Sharpyl Dak deposition on the eastern side of the basin; southward paleocurrent directions there suggest the eastward growth of the Kungey range in the Pliocene. Increased subsidence on the southern side of the basin and local tectonically 1194 | EAGE KUDRIAVTSEVA et al.