Reverse osmosis operations for water treatment are usually energy intensive and responsible for most of the product price. Several studies used flow characteristics to compare different geometries of feed spacers, but these cannot completely explain the effectiveness of feed spacers for promoting mass transfer near membranes. A few recent studies introduced a concept (Spacer Configuration Efficacy, SCE) combining mass transfer and energy consumption, but SCE has been applied only to a limited extent. The present study uses 3-dimensional steady state Computational Fluid Dynamics with mass transfer to compare four channels with feed spacer configurations (Ladder-type, Triple, Wavy and Submerged) and an empty plain channel using SCE and other performance measures. In contrast to previous studies, a saturated concentration boundary condition is employed at the membrane surface and optimised meshing of the domain is discussed. Power law correlations for SCE and other performance measures developed from the simulation results enable quick evaluation of the spacers. Results indicated that the assumed saturated solute concentration at the membrane strongly affects the mass transfer coefficient. Based on SCE, the Wavy spacer configuration showed the highest performance for Re > 120 among the obstructed geometries considered, while Ladder-type was better for Re < 120.
Electrospinning is a simple and versatile fiber synthesis technique in which a highvoltage electric field is applied to a stream of polymer melt or polymer solution, resulting in the formation of continuous micro/nanofibers. Halloysite nanotubes (HNT) have been found to achieve improved structural and mechanical properties when embedded into various polymer matrices. This research work focuses on blending poly(ε-caprolactone) (PCL) (9 wt%/v and 15 wt%/v) and poly(lactic acid) (PLA) (fixed at 8 wt%/v) solutions with HNT at two different concentrations 1 wt%/v and 2 wt%/v. Both unmodified HNT and HNT modified with 3-aminopropyltriethoxysilane (ASP) were utilized in this study. Furthermore, the addition of HNT-ASP to the polymeric blends resulted in a moderate decrease in the degree of crystallinity, as well as slight reductions of glass transition temperature of PCL, the crystallization temperature and melting temperature of PLA within composite materials. The infrared spectra of composites confirmed the successful embedding of HNT-ASP into PLA: PCL nanofibers relative to unmodified HNT due to the premodification using ASP to reduce the agglomeration behavior. This study provides a new material system that could be potentially used in drug delivery, and may facilitate good control of the drug release process.
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