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Highlights TiO 2 catalysts co-doped with La and V were synthesized using microwave-assisted hydrothermal process. Changes in the morphology and photocatalytic activity were observed as amount of both dopants were altered. The catalyst with 2% w/w La and 0.02% w/w V appeared to be the most photoactive. V-La co-doped TiO 2 was easily separable by settling down and showed good stability and reusability.