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A prototype broadband geodetic very long baseline interferometry system has been implemented, and measurements of the baseline length over approximately two years, between December 2014 and January 2017, have been made in the process of exercising the system, developing operational procedures, and assessing geodetic precision for the new broadband observing concept. In addition to developing a broadband signal chain and installing the instrumentation on both a new 12-m antenna at the Goddard Geophysical and Astrophysical Observatory and the 18-m Westford antenna at the Massachusetts Institute of Technology Haystack Observatory, it was necessary to develop new correlation and analysis procedures to process the four-band, dual-linear-polarization data. A geodetic analysis of the data from 19 sessions that were observed during this period yielded a weighted root-mean-square deviation of the baseline length residuals about the weighted mean of 1.6 mm. These results validate several of the expectations set forth for the vision of the next-generation geodetic very long baseline interferometry system. Derome, M., et al. (2018). Demonstration of a broadband very long baseline interferometer system: A new instrument for high-precision space geodesy.

The influence of organic-hexavalent-uranium [U(VI)] complexation on U(VI) reduction by a sulfate-reducing bacterium (Desulfovibrio desulfuricans) and an iron-reducing bacterium (Shewanella alga) was evaluated. Four aliphatic ligands (acetate, malonate, oxalate, and citrate) and an aromatic ligand (tiron [4,5-dihydroxy-1,3-benzene disulfonic acid]) were used to study complexed-uranium bioavailability. The trends in uranium reduction varied with the nature and the amount of U(VI)-organic complex formed and the type of bacteria present. D. desulfuricans rapidly reduced uranium from a monodentate aliphatic (acetate) complex. However, reduction from multidentate aliphatic complexes (malonate, oxalate, and citrate) was slower. A decrease in the amount of organic-U(VI) complex in solution significantly increased the rate of reduction. S. alga reduced uranium more rapidly from multidentate aliphatic complexes than from monodentate aliphatic complexes. The rate of reduction decreased with a decrease in the amount of multidentate complexes present. Uranium from an aromatic (tiron) complex was readily available for reduction by D. desulfuricans, while an insignificant level of U(VI) from the tiron complex was reduced by S. alga. These results indicate that selection of bacteria for rapid uranium reduction will depend on the organic composition of waste streams.