Digital divide, the differential in access and use of information and communication technologies (ICT) represents an obstacle to the information society, and general wellbeing. This study combines the extended unified theory of acceptance, and use of technology (UTAUT2) (Venkatesh, Thong, & Xu, 2012), Schwartz's basic human values theory (Schwartz, 1992) and ICT skills to: (1) understand which factors influence ICT acceptance among individuals; (2) explore the role of basic values on ICT acceptance; and, (3) examine how these factors explain the digital divide. The research model was tested in the context of a sub-Saharan country. Empirical results suggest that ICT use is mainly influenced by behavioral intention, habit, and ICT skills. Hedonism, achievement, benevolence, and universalism were the most significant values.