Reclaimed Asphalt Pavement (RAP) material mainly consists of removed asphalt concretes from existing infrastructures and, to a minor extent, of wasted or rejected mixes during the production processes. Being composed of two valuable non-renewable resources, i.e., aggregates and bituminous binder, its conscious use can ensure the sustainability of asphalt pavement construction. Thanks to the use of RAP material in new asphalt products, the USA saved 4.1 million tons of virgin binder and 78 million tons of virgin aggregates in 2018. Therefore, the use of RAP for the production of new asphalt formulations at the top of the recycling hierarchy is preferable instead of being down-cycled in low-value applications. The RAP material represents one of the most re-used construction products worldwide; in 2018, approximately 88% wt. and 72% wt. of RAP were used in USA and Europe, respectively, as aggregates for Hot, Warm and Cold Asphalt Mixtures and for unbound layers. Several studies have revealed positive responses of the recycled asphalt mixtures with high or very high content of RAP. However, the common practices of many countries still limit the RAP content to a 15–20% wt., on average, in the recycled asphalt mixes. The amount of RAP in asphalt concretes can be significantly increased by applying good management practices of the RAP, either processed or not, as well as novel production technologies and advanced mix design approaches. This manuscript aims to summarize the state-of-the-art of use of RAP aggregates in new asphalt mixtures. The economic and environmental benefits are also discussed.

Bitumen undergoes ageing, which leads to changes in its chemical and rheological properties, thus becoming harder and more brittle in time. This study aims to compare the effects of different laboratory ageing methods on chemistry and rheology of three bitumen types, i.e. a Pen 40/60, a Pen 70/100 and a polymer modified bitumen (PmB). Four ageing protocols were applied: ageing at room temperature, oven ageing, the Pressure Ageing Vessel (PAV), and the Rolling Thin Film Oven Test (RTFOT) combined with PAV ageing. The effects of temperature, pressure, and ageing time were studied using dynamic shear tests and infrared spectroscopy. The results highlight the relationship between chemistry and rheology of bitumen.Bitumen hardening, which was revealed by an increase in complex modulus and a decrease in phase angle, was reflected in the growth of specific chemical functional groups. Among all materials, soft bitumen showed the greater tendency to oxidize. Different behaviour was observed for PmB that presented the highest resistance against oxidation among the studied bitumens, even though the reaction with oxygen caused the deterioration of the added polymer modifiers.

Thanks to greater attention to the environment and the depletion of non-renewable resources, the sustainability and the circular economy have become crucial topics. The current trend of pavement engineering is to reduce the use of standard bitumen by replacing it with more sustainable materials such as industrial residues and by-products. In this regard, the present study aims to characterize innovative extended bitumen using recycled materials. Due to promising preliminary results as bitumen modifiers, the powdered rubber from end-of-life tires and the re-refined engine oil bottom (REOB) have been investigated as feasible components of bitumen extenders. Nevertheless, several variables strongly affect the performance of the resulting binder, which cannot be neglected. Hence, this research focuses on the rubber-REOB interaction in order to evaluate their optimum ratio, which may maximize the use and advantages of both recycled materials as suitable partial replacements for bitumen. Various rubber-REOB ratios were considered and investigated by means of low and high frequency nuclear magnetic resonance (NMR) spectrometers and scanning electron microscope (SEM).

Asphalt pavements inevitably deteriorate over time, requiring frequent maintenance work to ensure the proper serviceability of the road network. Small interventions, such as resurfacing for pavement preservation, are preferable to reconstruction at the end of roads’ in-service lives as they limit environmental- and economic-related impacts. Thin asphalt overlay (TAO) mixture represents a suitable maintenance solution to restore the functional properties of road surfaces. Due to the increasing awareness of the depletion of non-renewable resources and the importance of promoting the circular economy, this study evaluated the possibility of using fully recycled TAO mixes by investigating their volumetric and mechanical properties. Two eco-friendly TAO mixes were designed using recycled aggregates from reclaimed asphalt pavements, a municipal solid waste incinerator, and steel slags in order to meet EN 13108-2 requirements. The TAO mixes differed in regard to the type of bituminous binder (neat/SBS-modified bitumens) and fibres (natural/synthetic) employed. The preliminary results demonstrated that the presence of recycled aggregates did not negatively affect the workability and the mechanical performances of the two sustainable mixtures in terms of stiffness, tensile resistance, rutting and moisture susceptibility. Of these, the TAO mix with neat bitumen and synthetic fibres showed enhanced mechanical performance highlighting the structural effects of the used fibres.

Moisture sorption can significantly influence hydrothermal ageing and alter the chemical and rheological properties of bituminous mastics. Mineral filler particles are added to bituminous binders to form mastics with increased stiffness. The addition of fillers can considerably change the moisture sorption and the physico-chemical properties of binders by surface interactions and physical presence. This study aims to investigate the effect of filler type on the moisture-induced changes of bituminous mastics after wetting-drying cycles by means of sorption, rheological and infrared spectrometry tests. The results show that mineral fillers with higher diffusivity increase the overall capacity of mastics to absorb moisture, but at the same time allow for moisture desorption during drying. Nevertheless, it has been found that it is not the diffusivity properties but rather the bitumen and filler interactions that control the hydrothermal ageing of the mastics.

Recent studies have worked towards addressing environmental issues such as global warming and greenhouse gas emissions due to the increasing awareness of the depletion of natural resources. The asphalt industry is seeking to implement measures to reduce its carbon footprint and to promote sustainable operations. The reuse of several wastes and by-products is an example of a more eco-friendly activity that fulfils the circular economy principle. Among all possible solutions, the road pavement sector encourages, on one hand, the use of recycled materials as a partial replacement of the virgin lithic skeleton; on the other hand, it promotes the use of recycled materials to substituting for a portion of the petroleum bituminous binder. This study aims to use Re-refined Engine Oil Bottoms (REOBs) as a main substitute and additives from various industrial by-products as a full replacement for virgin bitumen, producing high-performing alternative binders. The REOBs have been improved by utilizing additives in an attempt to improve their specific properties and thus to bridge the gap between REOBs and traditional bituminous binders. An even larger amount of virgin and non-renewable resources can be saved using these new potential alternative binders together with the RAP aggregates. Thus, the reduction in the use of virgin materials is applied at the binder and the asphalt mixture levels. Rheological, spectroscopic, thermogravimetric, and mechanical analysis were used to characterize the properties, composition, and characteristics of the REOBs, REOB-modified binders, and asphalt mixes. Thanks to the rheological investigations of possible alternative binders, 18 blends were selected, since they behaved like an SBS-modified bitumen, and then they were used for producing the corresponding asphalt mixtures. The preliminary mechanical analysis of the asphalt mixtures shows that six mixes have promising responses in terms of stiffness, tensile resistance, and water susceptibility. Nevertheless, the high variability of recycled materials and by-products has to be taken into consideration during the definition of alternative binders and recycled asphalt mixtures. In fact, this study highlights the crucial effects of the chemical composition of the constituents and their compatibility on the behaviour of the final product. This preliminary study represents a first attempt to define alternative binders, which can be used in combination with recycled aggregates for producing more sustainable road materials. However, further analysis is necessary in order to assess the durability and the ageing tendency of the materials.

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Several studies aimed to improve both the performance and environmental impact of asphalt pavements using waste and recycled materials as fillers. This study focused on the effect of untreated and thermally treated silt as a filler in hot mix asphalt (HMA). The silt used in the study was a byproduct from a local aggregate production plant in Bologna, Italy. Mineral and chemical analyses revealed that the waste silt required thermal treatment at 750 °C for 2 h. The study compared the use of calcined silt, untreated silt, and a common limestone filler in the production of asphalt mastics and HMA specimens. The rheological properties of the mastics were analyzed using frequency sweep and multiple stress creep recovery tests. The physical and mechanical characteristics of the HMAs were evaluated through the air voids content, Marshall stability and indirect tensile strength tests. Additionally, the water susceptibility and thermal sensitivity of the HMAs were evaluated through the indirect tensile strength ratio and indirect tensile stiffness modulus at different testing temperatures. The results showed that the addition of calcined silt had no significant effect on the rheological properties of the mastic or the optimal binder content. However, the samples produced with thermally treated silt showed the highest stiffness and resistance to rutting compared with the other samples. On the other hand, the addition of untreated silt slightly decreased the stiffness value of the samples. In conclusion, the use of waste silt as a filler has potential as a sustainable and eco-friendly solution for HMAs.