Sustainable development is the common goal of the current concepts of bioeconomy and circular economy. In this sense, the biorefineries platforms are a strategic factor to increase the bioeconomy in the economic balance. The incorporation of renewable sources to produce fuels, chemicals, and energy, includes sustainability, reduction of greenhouse gases (GHG), and creating more manufacturing jobs fostering the advancement of regional and social systems by implementing the comprehensive use of available biomass, due to its low costs and high availability. This paper describes the emerging biorefinery strategies to produce fuels (bio-ethanol and γ-valerolactone) and energy (pellets and steam), compared with the currently established biorefineries designed for fuels, pellets, and steam. The focus is on the state of the art of biofuels and energy production and environmental factors, as well as a discussion about the main conversion technologies, production strategies, and barriers. Through the implementation of biorefineries platforms and the evaluation of low environmental impact technologies and processes, new sustainable production strategies for biofuels and energy can be established, making these biobased industries into more competitive alternatives, and improving the economy of the current value chains.

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Gamma-valerolactone (GVL) is a highly reactive keto-lactone and a promising platform biomolecule, used as an additive for food and fuels, green solvent, and fuels precursor, among others. Its production from biomass usually involves hydrogenation and subsequent cyclization of levulinic acid or its esters. The process of conventional hydrogenation requires high pressures and temperatures, an external hydrogen source, and scarce noble/precious materials as catalysts. However, it could be produced under mild conditions, using bifunctional metal-acid catalysts with high metal dispersion and meso or microporosity, high surface area, temperatures lower than 200 °C, pressures ≤ 1MPa, and secondary alcohols (such as isopropanol) as hydrogen donors. The catalytic transfer hydrogenation followed by cyclization (CTHC) of levulinic acid (LA) and its esters (LE) to produce GVL using secondary alcohols as H donor is a great alternative. Variables involved in CTHC such as raw material, time, temperature, and type of catalyst, mainly transition metals and their combinations, are reviewed in this work.

Gamma-valerolactone (GVL) is a highly reactive keto-lactone and a promising platform biomolecule, used as an additive for food and fuels, green solvent, and fuels precursor, among others. Its production from biomass usually involves hydrogenation and subsequent cyclization of levulinic acid or its esters. The process of conventional hydrogenation requires high pressures and temperatures, an external hydrogen source, and scarce noble/precious materials as catalysts. However, it could be produced under mild conditions, using bifunctional metal-acid catalysts with high metal dispersion and meso or microporosity, high surface area, temperatures lower than 200 °C, pressures ≤ 1MPa, and secondary alcohols (such as isopropanol) as hydrogen donors. The catalytic transfer hydrogenation followed by cyclization (CTHC) of levulinic acid (LA) and its esters (LE) to produce GVL using secondary alcohols as H donor is a great alternative. Variables involved in CTHC such as raw material, time, temperature, and type of catalyst, mainly transition metals and their combinations, are reviewed in this work.