In the membrane processes, a trans-membrane pressure (TMP) may arise due to design features or operating conditions. In most applications, stacks for electrodialysis (ED) or reverse electrodialysis (RED) operate at low TMP (<0.1 bar); however, large stacks with non-parallel flow patterns and/or asymmetric configurations can exhibit higher TMP values, causing membrane deformations and changes in fluid dynamics and transport phenomena. In this work, integrated mechanical and fluid dynamics simulations were performed to investigate the TMP effects on deformation, flow and mass transfer for a profiled membrane-fluid channel system with geometrical and mechanical features and fluid velocities representative of ED/RED conditions. First, a conservatively high value of TMP was assumed, and mechanical simulations were conducted to identify the geometry with the largest pitch to height ratio still able to bear this load without exhibiting a contact between opposite membranes. The selected geometry was then investigated under expansion and compression conditions in a TMP range encompassing most practical applications. Finally, friction and mass transfer coefficients in the deformed channel were predicted by computational fluid dynamics. Significant effects of membrane deformation were observed: friction and mass transfer coefficients increased in the compressed channel, while they decreased (though to a lesser extent) in the expanded channel.

Power systems in the future are expected to be characterized by an increasing penetration of renewable energy sources systems. To achieve the ambitious goals of the “clean energy transition”, energy storage is a key factor, needed in power system design and operation as well as power-to-heat, allowing more flexibility linking the power networks and the heating/cooling demands. Thermochemical systems coupled to power-to-heat are receiving an increasing attention due to their better performance in comparison with sensible and latent heat storage technologies, in particular, in terms of storage time dynamics and energy density. In this work, a comprehensive review of the state of art of theoretical, experimental and numerical studies available in literature on thermochemical thermal energy storage systems and their use in power-to-heat applications is presented with a focus on applications with renewable energy sources. The paper shows that a series of advantages such as additional flexibility, load management, power quality, continuous power supply and a better use of variable renewable energy sources could be crucial elements to increase the commercial profitability of these storage systems. Moreover, specific challenges, i.e., life span and stability of storage material and high cost of power-to-heat/thermochemical systems must be taken in consideration to increase the technology readiness level of this emerging concept of energy systems integration.

In electro-membrane processes, a pressure difference may arise between solutions flowing in alternate channels. This transmembrane pressure (TMP) causes a deformation of the membranes and of the fluid compartments. This, in turn, affects pressure losses and mass transfer rates with respect to undeformed conditions and may result in uneven flow rate and mass flux distributions. These phenomena were analyzed here for round pillar-type profiled membranes by integrated mechanical and fluid dynamics simulations. The analysis involved three steps: (1) A conservatively large value of TMP was imposed, and mechanical simulations were performed to identify the geometry with the minimum pillar density still able to withstand this TMP without collapsing (i.e., without exhibiting contacts between opposite membranes); (2) the geometry thus identified was subject to expansion and compression conditions in a TMP interval including the values expected in practical applications, and for each TMP, the corresponding deformed configuration was predicted; and (3) for each computed deformed configuration, flow and mass transfer were predicted by computational fluid dynamics. Membrane deformation was found to have important effects; friction and mass transfer coefficients generally increased in compressed channels and decreased in expanded channels, while a more complex behavior was obtained for mass transfer coefficients.

The transition to a sustainable society and a carbon-neutral economy by 2050 requires extensive deployment of renewable energy sources that, due to the aleatority and non-programmability of most of them, may seriously affect the stability of existing power grids. In this context, buildings are increasingly being seen as a potential source of energy flexibility for the power grid. In literature, key performance indicators, allowing different aspects of the load management, are used to investigate buildings’ energy flexibility. The paper reviews existing indicators developed in the context of theoretical, experimental and numerical studies on flexible buildings, outlining the current status and the potential future perspective. Moreover, the paper briefly reviews the range of grid services that flexible buildings can provide to support the reliability of the electric power system which is potentially challenged by the increasing interconnection of distributed variable renewable generation.

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Ventilated Faç ades integrated with photovoltaic panels have become a popular way to improve both the thermal-physical performances of the existing built environment. The increased usage of not-programmable renewable energy sources implies the adoption of energy storage systems to mitigate the mismatch between the power generation and the building's demand. Aiming at properly integrates a photovoltaic panel and a battery (Lithium based) as a module of an active ventilated faç ade, the prototype design has been carried out in terms of thermo-fluid dynamics performance. Based on experimental setup, a numerical study of flow through the air cavity of the active ventilated faç ade has been carried out by the fluid-dynamics Finite Volume code-Ansys-Fluent. The calibrated model was lastly used to perform a wide range of parametric analyses on different climate and boundary conditions to explore the viability of the prototype.

In this paper, cement mortar IN200 integrated with solid–solid PlusIce X25 commercial PCM was fully characterized for the first time via experimental tests and numerical simulations. An experimental setup was designed and built to evaluate the thermal performance of the composite. Experimental results confirmed the expected advantages of the PCM-loaded plaster in terms of inner surface temperature, inbound heat flux reduction, and the enhanced damping effect on the average temperature. The experimental results were used to validate and calibrate a finite element model implemented in COMSOL Multiphysics® 5.6. The model was adopted to carry out a parametric analysis assessing the influence of PCM mass fraction, phase transition temperature, and PCM mortar thickness. The composite thickness was the most influential parameter, resulting in an energy saving increase from 3.29% to 72.72% as it was increased from 10 mm to 30 mm. Moreover, the model was used in a set of dynamic simulations, reproducing real Mediterranean climatic conditions to capture the transition process for a long period in buildings. The PCM mortar located on the interior side exhibited the highest reduction in both heat flux and inner surface temperature, representing a simple approach to achieving the best thermal comfort conditions.

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