Lead halide perovskites (LHPs) are promising materials for opto-electronics and photovoltaics, thanks to favorable characteristics and low manufacturing costs enabled by solution processing. In light of this, it is crucial...

The bootstrap method has been applied to estimate error bounds on five goodness-of-fit indicators in vibrational spectroscopy. The use of these indicators has been first tested on the known vibrational circular dichroism spectrum of 3-chloro-1-butyne, and then it has been adopted for the assignment of the absolute configuration of 3-methyl-3-nitromethyl-isoindolinone. The (+) stereoisomer turns out to have the (S ) configuration.