Worldwide increased concern of the CO2 emissions has led to the replacement of coal by biomass in combustion-based power plants. However, this would cause the scarcity of fly ash, one of the most well-known rest products from coal combustion, which is used as supplementary cementitious materials (SCM) in construction sector to reduce the large environmental footprint of cement production. Seeking to find alternative SCMs, this article aims to demonstrate the viability of using bio ashes in Sweden as SCM, which, due to lack of studies validating their value, are landfilled today. According to the obtained results, bio ashes produced at pulp and paper industries have a considerably consistent chemical composition and exhibit a satisfactory pozzolanic behaviour. Nevertheless, according to the conclusions of this study, the pozzolanicity of these alternative binders is not reflected equally with respect to the most known reactivity tests for common SCMs. The results imply that although “R3” tests method infers the pozzolanic characteristics of the bio ashes in focus of this study, the “activity index test” as well as “calcium consumption test” indicate otherwise.
Considerable leaching of alkali metals was documented, both in concrete samples exposed to accelerated laboratory testing and field samples. CWE allowed to quantitatively determine the free alkali metal profiles as a function of the depth. However, CWE cannot account for the changes in the paste content towards a cast surface leading to a seemingly increase in alkali metals. The µXRF allowed to distinguish paste and aggregates. It allowed thereby to determine qualitative Na and K profiles in the cement paste phase of the concrete samples. The laboratory exposed samples showed a clear leaching profile into a depth of about 15 mm after 21 weeks of exposure at 60 °C. Corresponding numbers for the 12 years field exposed cube were 50-60 mm. Alkali sorption by alkali silica gel was detected using the µXRF. For the laboratory exposed samples, the prisms prepared with Portland fly ash cement leached less alkali compared to the prisms prepared with ordinary Portland cement, as expected. The leaching in the middle of the prisms estimated based on the µXRF profiles agreed rather well with the level of alkali leaching determined based on the analysis of the leachate (i.e. the water below the samples during exposure).
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