Livestock production is among the most rapidly growing sectors of the agricultural economy driven primarily by growing demand for animal protein, but also posing significant waste disposal issues and environmental impacts. Moreover, opportunities exist for utilising animal waste at the farm level for heat and power generation (thermal conversion) which can contribute to economic sustainability and also provide a bio-fertiliser for soil amendment. The present study is focused on energy and nutrient recovery from poultry litter using a thermochemical conversion technology (fast pyrolysis). The formation of products (gases, biochar and bio-oil) during the fast pyrolysis of poultry litter was experimentally investigated in a laboratory-scale bubbling fluidised bed reactor. Pyrolytic gases accounted for 15–22 wt.% of the product. The carbon content in biochar increased from 47 to 48.5 wt.% with an increase in the pyrolysis temperature. Phosphorous and potassium recovery in the biochar were over 75%, suggesting that it could be used as an organic soil amendment. The high ash content in poultry litter (14.3 wt.%) resulted in low bio-oil and high biochar yield. The bio-oil yield was over 27 wt.% with a higher heating value of 32.17 MJ/kg (dry basis). The total acid number of the bio-oil decreased from 46.30 to 38.50 with an increase in temperature. The nitrogen content in the bio-oil produced from the poultry litter (>7 wt.%) was significantly higher compared to bio-oil produced from the wood (0.1 wt.%).

Cite as: Katsaros, G., Nguyen, T.-V., Rokni, M., Tri-generation System based on Municipal Waste Gasification, Fuel Cell and an Absorption Chiller, J. sustain. dev. energy water environ. syst., 6(1), pp 13-32, 2018, DOI: http://dx.doi.org/10.13044/j.sdewes.d5.0172 ABSTRACTThe present work focuses on the design of a novel tri-generation system based on gasification of municipal solid wastes, a solid oxide fuel cell and an ammonia-water absorption chiller. Tri-generation systems can be implemented in buildings such as hospitals and hotels, where there is a continuous and large demand for electricity, heating and cooling. The system is modelled in Aspen Plus and the influence of different operating parameters on the system performance was studied. The findings suggest that low air equivalent ratios and high gasification temperatures enhance the overall system performance. Syngas cleaning with metal sorbents zinc oxide and sodium bicarbonate for the removal of hydrogen sulfide and hydrogen chloride concentrations proved to be very effective, reducing the concentration of contaminants to < 1 ppm (part per million) levels. The possibility of covering the demand profiles of a specific building was also investigated: the system could fully meet the electricity and cooling demands, whereas the heat requirements could be satisfied only up to 55%. Moreover, assuming 20 years of operation, the payback period was 4.5 years and the net present value exceeded 5 million euros.

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This paper investigates the integration of biosyngas production, reheating furnace and heat recovery steam cycle, in order to use biosyngas directly as fuel in the furnace. A system model was developed to evaluate the feasibility of the proposed system from the perspective of heat and mass balance. To particularly study the impacts of fuel switching on the heating quality of the furnace, a three-dimensional furnace model considering detailed heat transfer processes was embedded into the system through an Aspen Plus TM user defined model. The simulation results show that biosyngas is suitable for direct use as fuel for reheating furnaces. Should CO capture be considered in the proposed system, it has a potential to achieve the capture without external energy input which results in so-called negative emissions of CO .

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