It has recently been established that the high temperature (high-Tc(between atomic and macroscopic scale). Here we report micro X-ray diffraction imaging of the spatial distribution of both the charge-density-wave 'puddles' (domains with only a few wavelengths) and quenched disorder in HgBa 2 CuO 4+y , the single layer cuprate with the highest T c , 95 kelvin [26][27][28] . We found that the charge-density-wave puddles, like the steam bubbles in boiling water, have a fat-tailed size distribution that is typical of selforganization near a critical point 19 . However, the quenched disorder, which arises from oxygen interstitials, has a distribution that is contrary to the usual assumed random, uncorrelated distribution 12, 13 . The interstitials-oxygen-rich domains are spatially anticorrelated with the charge-density-wave domains, leading to a complex emergent geometry of the spatial landscape for superconductivity. 2Although it is known that the incommensurate charge-density-wave (CDW) order in cuprates (copper oxides) is made of ordered, stripy, nanoscale puddles with an average of only 3-4 oscillations, information about the size distribution and spatial organization of these puddles has so far not been available. We present experiments that demonstrate that CDW puddles, have a complex spatial distribution and coexist with, but are spatially anticorrelated to, quenched disorder in HgBa 2 CuO 4+y (Hg1201). The sample we studied is a layered perovskite at optimum doping with oxygen interstitials y=0.12, tetragonal symmetry P4/mmm and a low misfit strain [14][15][16] . The X-ray diffraction (XRD) measurements (see Methods) show diffuse CDW satellites (secondary peaks surrounding a main peak) at q CDW =(0.23a*, 0.16c*), in the b*=0 plane and q CDW =(0.23b*, 0.16c*) in the a*=0 plane (where a*, b*, and c* are the reciprocal lattice units) around specific Bragg peaks, such as (1 0 8), below the onset temperature T CDW =240 K (see Fig. 1a). The component of the momentum transfer q CDW in the CuO 2 plane (0.23a*) in this case is smaller than it is in the underdoped case (0.28a*) 5 . The temperature evolution of CDW-peak profile along a* (in the h direction; Fig. 1b) shows a smeared, glassy-like evolution below T CDW .The CDW-peak intensity reaches a maximum at T=100 K, followed by a drop associated with the onset of superconductivity at T=T c . We investigated the isotropic character of the CDW, in the a-b plane using azimuthal scans, as shown in Fig. 1c. We observed an equal probability of vertical and horizontally striped CDW puddles.Our main result is the discovery of the statistical spatial distribution of the CDW-puddle size and density throughout the sample, which shows an emergent complex network geometry for the superconducting phase. We performed scanning micro X-ray diffraction (SµXRD) measurements (see Methods) to extend the imaging of spatial inhomogeneity previously obtained by scanning tunneling microscopy [7][8][9] , from the surface to the bulk of the sample and from nanoscale to mesoscale spatial inh...
Advanced synchrotron radiation focusing down to a size of 300 nm has been used to visualize nanoscale phase separation in the K 0.8 Fe 1.6 Se 2 superconducting system using scanning nanofocus single-crystal X-ray diffraction. The results show an intrinsic phase separation in K 0.8 Fe 1.6 Se 2 single crystals at T< 520 K, revealing coexistence of i) a magnetic phase characterized by an expanded lattice with superstructures due to Fe vacancy ordering and ii) a non-magnetic phase with an in-plane compressed lattice. The spatial distribution of the two phases at 300 K shows a frustrated or arrested nature of the phase separation. The space-resolved imaging of the phase separation permitted us to provide a direct evidence of nanophase domains smaller than 300 nm and different micrometer-sized regions with percolating magnetic or nonmagnetic domains forming a multiscale complex network of the two phases.
Temperature dependent single-crystal x-ray diffraction (XRD) in transmission mode probing the bulk of the newly discovered K 0.8 Fe 1.6 Se 2 superconductor (T c = 31.8 K) using synchrotron radiation is reported. A clear evidence of intrinsic phase separation at 520 K between two competing phases, (i) a first majority magnetic phase with a ThCr 2 Si 2 -type tetragonal lattice modulated by the iron 5 × 5 vacancy ordering and (ii) a minority non-magnetic phase having an in-plane compressed lattice volume and a 2 × 2 weak superstructure, is reported. The XRD peaks due to the Fe vacancy 5 × 5 ordering in the majority phase disappear by increasing the temperature at 580 K, well above phase separation temperature confirming the order-disorder phase transition. The intrinsic phase separation at 520K between a competing first magnetic phase and a second non-magnetic phase in the normal phase both having lattice superstructures (that imply different Fermi surface topology reconstruction and charge density) is assigned to a lattice-electronic instability of the K 0.8 Fe 1.6 Se 2 system typical of a system tuned at a Lifshitz critical point of an electronic topological transition that gives a multi-gaps superconductor tuned a shape resonance. *
We report the temperature dependent x-ray powder diffraction of the quaternary compound NdOFeAs (also called NdFeAsO ) in the range between 300 K and 95 K. We have detected the structural phase transition from the tetragonal phase, with P4/nmm space group, to the orthorhombic or monoclinic phase, with Cmma or P112/a1 (or P2/c) space group, over a broad temperature range from 150 K to 120 K, centered at T 0 ~137 K. Therefore the temperature of this structural phase transition is strongly reduced, by about ~30K, by increasing the internal chemical pressure going from LaOFeAs to NdOFeAs. In contrast the superconducting critical temperature increases from 27 K to 51 K going from LaOFeAs to NdOFeAs doped samples. This result shows that the normal striped orthorhombic Cmma phase competes with the superconducting tetragonal phase. Therefore by controlling the internal chemical pressure in new materials it should be possible to push toward zero the critical temperature T 0 of the structural phase transition, giving the striped phase, in order to get superconductors with higher T c .
All-organic nanostructured host-guest systems, based on dyes inserted in the nanochannels of perhydrotriphenylene (PHTP) and deoxycholic acid (DCA), show enhanced fluorescence properties with quantum yields even higher than those of the dyes in solution, thanks to the high concentration of emissive molecules with controlled spatial and geometrical organization that prevents aggregation quenching. Both host molecules crystallize, growing with the long axis oriented along the direction of the nanochannels where the linear-chain dyes are inserted, to yield crystals emitting well-polarized light. For the DCA-based host-guests, homogeneous thin films suitable for several applications are obtained. Colour emission in such films can be tuned by co-inclusion of two or three dyes due to resonant energy-transfer processes. We show that films obtained by low-cost techniques, such as solution casting and spin-coating, convert UV light into visible light with an efficiency much higher than that of the standard polymeric blends.
Oil sources characterized of increasing viscosity and polarity (flax-seed oil, sunflower oil, extra virgin olive oil, triolein, castor oil) were gelled by using mixtures of β-sitosterol and γ-oryzanol (5, 10 and 20 % w/w). The gelling time, thermal properties as well as structure characteristics were determined. As the oil viscosity increased the gelling time increased. The effect of oil type resulted more evident as the structurant concentration decreased. Samples containing 5 % of the most viscous and polar castor oil did not gelled over the entire experiment. When gels were formed, the firmness of samples decreased in concomitance with modifications of thermal data as the oil viscosity increased. During storage at 20 °C the gels became stronger as consequence of the progression of the aggregation among sterol-sterol ester assemblages. Once again, less structurants were in the mixture more evident was the influence of oil type. These results were attributed to the increase of the difficulty of β-sitosterol and γ-oryzanol molecules to pack together as the oil viscosity increased
Graded bilayer solar cells have proven to be at least as efficient as the bulk heterojunctions when it comes to the Poly(3-hexylthiophene) (P3HT) - [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) donor-acceptor system. However, control of the vertical concentration gradient using simple techniques has never been reported. We demonstrate that rubbing the P3HT layer prior to PCBM deposition induces major morphological changes in the active layer. Using the newly introduced energy-dispersive X-ray spectroscopy element mapping technique, we found that rubbing P3HT induces the formation of an ideal vertical donor-acceptor concentration gradient. Furthermore, the P3HT crystallites undergo a molecular reorientation from edge-on to face-on configuration inducing a better charge transport in the vertical direction. The combination of these two major morphological changes leads to the fabrication of high-performance solar cells that exhibit, to date, the record efficiencies for spin-coated graded bilayers solar cells.
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