Microalgae (Spirulina) and primary sewage sludge are considerable feedstocks for future fuel-producing biorefinery. These feedstocks have either a high fuel production potential (algae) or a particularly high appearance as waste (sludge). Both feedstocks bring high loads of nutrients (P, N) that must be addressed in sound biorefinery concepts that primarily target specific hydrocarbons, such as liquid fuels. Hydrothermal liquefaction (HTL), which produces bio-crude oil that is ready for catalytic upgrading (e.g., for jet fuel), is a useful starting point for such an approach. As technology advances from small-scale batches to pilot-scale continuous operations, the aspect of nutrient recovery must be reconsidered. This research presents a full analysis of relevant nutrient flows between the product phases of HTL for the two aforementioned feedstocks on the basis of pilot-scale data. From a partial experimentally derived mass balance, initial strategies for recovering the most relevant nutrients (P, N) were developed and proofed in laboratory-scale. The experimental and theoretical data from the pilot and laboratory scales are combined to present the proof of concept and provide the first mass balances of an HTL-based biorefinery modular operation for producing fertilizer (struvite) as a value-added product.
Activated Carbon (AC) can be used to reduce organic micropollutants (OMPs) in wastewater treatment plants (WWTPs). While producing ACs conventionally still damages the environment, this can be reduced by using renewable raw material from waste streams und producing AC locally. In this study, fibers (toilet paper) were separated out of wastewater by screening WWTP influents in full scale and then used as a no-cost, carbon-rich and heavy metal-poor raw material to produce ACs. Pretreatment was hydrothermal carbonization (HTC). Thereafter, they were activated using KOH to generate activated carbons (HTC-ACs). Their functional groups were characterized using FT-IR, and the alteration of their chemical composition was traced by elementary analysis. Adsorption tests were performed with nitrogen (BET surface) and methylene blue as standard tests. The adsorption capacity was tested with WWTP effluent and the removal of UVA as a surrogate for OMP removal was measured. After HTC and activation 13-16% of the fibers dry mass was obtained as HTC-ACs. Higher dehydration and formation of aromatic structures on the HTC-ACs were detected with FT-IR as HTC and activation temperature increased. BET surface and methylene blue adsorption of some HTC-ACs was higher than the Reference AC. Nevertheless, their ability to reduce OMPs is still lower than the Reference AC due to the different nature of their functional groups and their microporous structure that is not fully accessible for OMPs in real wastewater. Further research has to be carried out to adjust the production process so as to obtain mesoporous HTC-ACs tailored to reduce OMP concentrations and to close the carbon loop within WWTPs.
Organic micropollutants (MPs), in particular xenobiotics and their transformation products, have been detected in the aquatic environment and the main sources of these MPs are wastewater treatment plants. Therefore, an additional cleaning step is necessary. The use of activated carbon (AC) is one approach to providing this additional cleaning. Industrial AC derived from different carbonaceous materials is predominantly produced in low-income countries by polluting processes. In contrast, AC derived from sewage sludge by hydrothermal carbonization (HTC) is a regional and sustainable alternative, based on waste material. Our experiments demonstrate that the HTC-AC from sewage sludge was able to remove most of the applied MPs. In fact more than 50% of sulfamethoxazole, diclofenac and bezafibrate were removed from artificial water samples. With the same approach carbamazepine was eliminated to nearly 70% and atrazine more than 80%. In addition a pre-treated (phosphorus-reduced) HTC-AC was able to eliminate 80% of carbamazepine and diclofenac. Atrazine, sulfamethoxazole and bezafibrate were removed to more than 90%. Experiments using real wastewater samples with high organic content (11.1 g m(-3)) succeeded in proving the adsorption capability of phosphorus-reduced HTC-AC.
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