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The reaction of titanium(IV) alkoxides in 1:1 stoichiometry with 2-methyl-2,4-pen tan ediol, pyrocatechol, salicylic acid, or , '-diphenylmethylenediphosphinic acid yields chelates of the form Ti(BB)(OR)z, where BB represents the binegative bidentate ligands involved and R is ethyl or isopropyl. A similar reaction with 1,3-propanediol does not produce Ti-(OCaHeOXORk, but instead Ti(OCsHeOk and Ti(ORk are recovered. The Ti(BB)(ORk derivatives are all associated

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