Various types of solid-liquid phase change materials (PCMs) have been reviewed for thermal energy storage applications. The review has shown that organic solid-liquid PCMs have much more advantages and capabilities than inorganic PCMs but do possess low thermal conductivity and density as well as being flammable. Inorganic PCMs possess higher heat storage capacities and conductivities, cheaper and readily available as well as being non-flammable, but do experience supercooling and phase segregation problems during phase change process. The review has also shown that eutectic PCMs have unique advantage since their melting points can be adjusted. In addition, they have relatively high thermal conductivity and density but they possess low latent and specific heat capacities. Encapsulation technologies and shell materials have also been examined and limitations established. The morphology of particles was identified as a key influencing factor on the thermal and chemical stability and the mechanical strength of encapsulated PCMs. In general, in-situ polymerization method appears to offer the best technological approach in terms of encapsulation efficiency and structural integrity of core material. There is however the need for the development of enhancement methods and standardization of testing procedures for microencapsulated PCMs. Abstract: Various types of solid-liquid phase change materials (PCMs) have been reviewed for thermal energy storage applications. The review has shown that organic solid-liquid PCMs have much more advantages and capabilities than inorganic PCMs but do possess low thermal conductivity and density as well as being flammable. Inorganic PCMs possess higher heat storage capacities and conductivities, cheaper and readily available as well as being non-flammable, but do experience supercooling and phase segregation problems during phase change process. The review has also shown that eutectic PCMs have unique advantage since their melting points can be adjusted. In addition they have relatively high thermal conductivity and density but they possess low latent and specific heat capacities. Encapsulation technologies and shell materials have also been examined and limitations established. The morphology of particles were identified as a key influencing factor on the thermal and chemical stability and the mechanical strength of encapsulated PCMs. In general, in-situ polymerization method appears to offer the best technological approach in terms of encapsulation efficiency and structural integrity of core material. There is however the need for the development of enhancement methods and standardization of testing procedures for microencapsulated PCMs.

/npsi/ctrl?lang=en http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/ctrl?lang=fr Access and use of this website and the material on it are subject to the Terms and Conditions set forth at http://nparc.cisti-icist.nrc-cnrc.gc.ca/npsi/jsp/nparc_cp.jsp?lang=en NRC Publications Archive Archives des publications du CNRCThis publication could be one of several versions: author's original, accepted manuscript or the publisher's version. / La version de cette publication peut être l'une des suivantes : la version prépublication de l'auteur, la version acceptée du manuscrit ou la version de l'éditeur. For the publisher's version, please access the DOI link below./ Pour consulter la version de l'éditeur, utilisez le lien DOI ci-dessous.http://dx.doi.org/10.1016/j.buildenv. 2006.06.025 Building and Environment, 43, 4, pp. 601-609, 2008-04-01 History and development of validation with the ESP-r simulation program Strachan, P. A.; Kokogiannakis, G.; Macdonald, I. A. A version of this document is published in / Une version de ce document se trouve dans: Building and Environment, v. 43, no. 4, April 2008, pp. 601-609 doi: 10.1016/j.buildenv.2006 The material in this document is covered by the provisions of the Copyright Act, by Canadian laws, policies, regulations and international agreements. Such provisions serve to identify the information source and, in specific instances, to prohibit reproduction of materials without written permission.

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The CEN Standards that support the European Energy Performance of Buildings Directive requirement for calculation of the energy consumption of buildings allow various methods to be used for the same calculation. The impact of using the different methods within the updated ISO 13790 Standard for space heating and cooling energy calculations was examined with a parametric analysis of a common building specification. The impact was assessed by considering the energy band which would be assigned for the building based on the calculation results. The Standard describes three different methods that can be used for the calculations: a monthly quasi-steady state method, a simplified hourly method and detailed simulation. For most cases studied, differences in the building rating given by the various methods were a maximum of one band. More significant differences were noticed in some cases. Parameter values in the monthly method were determined which would lead to improved matching

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Phase change material emulsions (PCMEs) are multifunctional fluids consisting of phase change materials (PCMs) and carrier fluids. PCMEs could be potential candidates as heat transfer media in heating, ventilation and air conditioning (HVAC) systems. This is mainly because PCME could take advantage of its high heat capacity to reduce flow rate and thus saving pumping power whilst delivering the same amount of cooling effect. PCME can also simultaneously act as cold storage to shift peak-load to off-peak time and improve the COP of systems. However, the optimum design of integrated system requires a good understanding of flow behaviour and heat transfer characteristics of PCMEs. In this paper, comprehensive reviews of their thermophysical properties and potential applications as thermal energy storage and as alternative heat transfer fluids in air conditioning systems have been carried out to establish their limitations for future research. systems. This is mainly because PCME could take advantage of its high heat capacity to reduce flow rate and thus saving pumping power whilst delivering the same amount of cooling effect. PCME can also simultaneously act as cold storage to shift peak-load to off-peak time and improve the COP of systems. However, the optimum design of integrated system requires a good understanding of flow behaviour and heat transfer characteristics of PCMEs. In this paper, comprehensive reviews of their thermo-physical properties and potential applications as thermal energy storage and as alternative heat transfer fluids in air conditioning systems have been carried out to establish their limitations for future research.

In this paper a novel microencapsulated phase change material (MF-3) has been developed and tested for solar assisted hot water storage systems. Even though the morphology of the sample was affected by the type of emulsifier used for fabrication it recorded the highest energy storage capacity of 126 kJ/kg with encapsulation efficiency of 97.4% as compared with other developed samples. For the purpose of assessing its thermal effectiveness it was theoretically evaluated in a compacted fixed bed TES unit and found to be capable of achieving a higher energy storage density as well as relatively smaller physical storage size than water based system. Despite the overall effective thermal conductivity being slightly less than water, its value was still about twice as high as most current PCM storage units. Experimental evaluation is therefore strongly encouraged.