Abstract:The major strengthening mechanisms in bainitic steels arise from the bainitic ferrite plate thickness rather than the length, which primarily determines the mean free slip distance. Both the strength of the austenite from where the bainite grows and the driving force of the transformation, are the two factors controlling the final scale of the bainitic microstructure. Usually, those two parameters can be tailored by means of selection of chemical composition and transformation temperature. However, there is also the possibility of introducing plastic deformation on austenite and prior to the bainitic transformation as a way to enhance both the austenite strength and the driving force for the transformation; the latter by introducing a mechanical component to the free energy change. This process, known as ausforming, has awoken a great deal of interest and it is the object of ongoing research with two clear aims. First, an acceleration of the sluggish bainitic transformation observed typically in high C steels (0.7-1 wt. %) transformed at relatively low temperatures. Second, to extend the concept of nanostructured bainite from those of high C steels to much lower C contents, 0.4-0.5 wt. %, keeping a wider range of applications in view.Keywords: bainite; ausforming; kinetics; plate thickness Structural Refinement of Bainitic Steels: General ConsiderationsBainitic steels can be designed on the basis of the theory that predicts the highest temperature at which bainite (Bs) and martensite (Ms) can start to form in a steel of a given composition. These two temperatures constitute the upper and lower limits at which the isothermal heat treatment can be performed to generate bainite.It has been reported that bainitic ferrite plate thickness depends primarily on three parameters, i.e., (1) the strength of the austenite at the transformation temperature, (2) the dislocation density in the austenite and (3) the chemical free energy change accompanying transformation [1][2][3]. In accord, a strong austenite possessing a high dislocation density and a large driving force results in finer plates. Austenite strength and dislocation density refine the structure by increasing the resistance to interface motion, and the thermodynamic driving force refines the structure by increasing the nucleation rate. All three factors-austenite strength, dislocation density and driving force-increase
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.Most applications of thermodynamic databases to materials design are limited to ambient pressure. The consideration of elastic contributions to thermodynamic stability is highly desirable but not straight-forward to realise. We present examples of existing physical models for pressure-dependent thermodynamic functions and discuss the requirements for future implementations given the existing results of experiments and first-principles calculations. We briefly summarize the calculation of elastic constants and point out examples of nonlinear variation with pressure, temperature and chemical composition that would need to be accounted for in thermodynamic databases. This is particularly the case if a system melts from different phases at different pressures. Similar relations exist between pressure and magnetism and hence set the need to also include magnetic effects in thermodynamic databases for finite pressure. We present examples to illustrate that the effect of magnetism on stability is strongly coupled to pressure, temperature, and external fields. As a further complication we discuss dynamical instabilities that may appear at finite pressure. While imaginary phonon frequencies may render a structure unstable and destroy a crystal lattice, the anharmonic effects may stabilize it again at finite temperature. Finally, we also outline a possible implementation scheme for strain effects in thermodynamic databases.
In this contribution strain induced precipitation of niobium carbides has been analyzed making use of different hot-rolling simulators and combining the advanced precipitation characterization methods of selective chemical extraction and transmission electron microscopy. A laboratory cast Fe-0.1C-0.07Nb alloy has been employed for the study. Thermomechanical simulations were carried out by torsion, plastodilatometry and plane strain compression techniques. The results have shown that, in spite of the different deformation modes a relatively good correlation is obtained between the measurements of the precipitate size and the amount of Nb precipitated in the different experiments.
The present paper contributes in the discussion of heterogeneous gas/metal reactions by discussing the influence of the dew point (dp) during intercritical annealing on the sub-surface constitution. Annealing trials with different Advanced High Strength Steels (AHSS) were carried out and the element distribution within the sub-surface was analysed by glow discharge optical emission spectrometer (GD-OES). For modelling purpose the gained element distribution data were adjusted in a way that the selective oxidation products were considered within the sub-surface element profiles. Several transformation temperatures along the depth profiles according to the adjusted GD-OES data have been computed for the dp À30 8C and þ5 8C. In all cases the according models have been implemented in Matlab. The thermodynamic data have been obtained via the Matlab-ThermoCalc interface. Empirical equations have been applied for the determination of the bainite and martensite start temperatures. It is shown that the sub-surface constitution and the transformation temperature differ significantly. In most cases the change of the transformation temperature within the surface and sub-surface reaches up to 100 8C compared to the bulk. For a Dual-Phase (DP) Steel with C(0.15%)Mn(1.7%)Al(1.7%)Cr(0.5%), the change of the A e1 -temperature is with 300 8C significantly higher. However one has to keep in mind that the 2-phase composition can not be assumed to be constant during intercritical annealing. It is therefore concluded that for the purpose of simulating the selective oxidation processes during intercritical annealing of AHSS the continuous change of the sub-surface constitution must be incorporated in the future work.
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