The lanthanide contraction is conceptualized traditionally through coordination chemistry. Here we break this mold in a structural study of lanthanide ions dissolved in an amphiphilic liquid. The lanthanide contraction perturbs the weak interactions between molecular aggregates that drive mesoscale assembly and emergent behavior. The weak interactions correlate with lanthanide ion transport properties, suggesting new strategies for rare-earth separation that exploit forces outside of the coordination sphere.
Controlling the assembly of soft
and deformable molecular aggregates
into mesoscale structures is essential for understanding and developing
a broad range of processes including rare earth extraction and cleaning
of water, as well as for developing materials with unique properties.
By combined synchrotron small- and wide-angle X-ray scattering with
large-scale atomistic molecular dynamics simulations we analyze here
a metalloamphiphile–oil solution that organizes on multiple
length scales. The molecules associate into aggregates, and aggregates
flocculate into meso-ordered phases. Our study demonstrates that dipolar
interactions, centered on the amphiphile headgroup, bridge ionic aggregate
cores and drive aggregate flocculation. By identifying specific intermolecular
interactions that drive mesoscale ordering in solution, we bridge
two different length scales that are classically addressed separately.
Our results highlight the importance of individual intermolecular
interactions in driving mesoscale ordering.
Knowledge of the supramolecular structure of the organic phase containing amphiphilic ligand molecules is mandatory for full comprehension of ionic separation during solvent extraction. Existing structural models are based on simple geometric aggregates, but no consensus exists on the interaction potentials. Herein, we show that molecular dynamics crossed with scattering techniques offers key insight into the complex fluid involving weak interactions without any long-range ordering. Two systems containing mono- or diamide extractants in heptane and contacted with an aqueous phase were selected as examples to demonstrate the advantages of coupling the two approaches for furthering fundamental studies on solvent extraction.
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