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The hydroboration of CO2 into bis(boryl)acetal (BBA) compounds is an important transformation, since it enabled to selectively reduce CO2 by 4e‐ and to subsequently use the BBA compounds as C1 and Cn sources. However, the influence of the nature of the boryl moieties on the reactivity of BBA compounds has not been evaluated so far. In the present study, four BBA compounds – including two new ones – were reacted with 2,6‐diisopropylaniline to afford the expected imine. Significant differences in the rate of the reaction from minutes to weeks have been observed depending on the BBA used, showing the importance of the nature of the boryl moieties. Theoretical investigations enabled to propose a mechanism involving the addition of the aniline to the BBA as the rate‐determining step and to determine that the steric hindrance of the BBA compounds is the main factor driving the rate of this condensation reaction.

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Abstract-The composite backscattering of the ship model on sea surface is investigated with the spilling breaking waves and ship bow waves. The spilling breakers are approximately modeled with the wedge-like waves, and the ship bow waves are simulated based on the Kelvin model. With the modified four-path model, each scattering component is evaluated with the high frequency approximation methods for the total composite scattering. Due to the volume scattering, the composite scattering at large incidence angles is strongly enhanced by the non-Bragg scattering. The relationship of the composite scattering and the ship motion is analyzed. The numerical results of sea surface scattering agree with the measured data well, and the complex physical mechanism of the low-grazing-angle composite scattering is explicitly evaluated in this paper.