Inorganic perovskite quantum dots (QDs) have natural advantages in the field of light-emitting diodes (LEDs) because of their high color purity and tunability in a wide range. However, when manufacturing efficiently mixedanion perovskite QDs (CsPbBr x I 3−x ) to meet the requirements of the pure red color standard in the display field (≈630 nm), results are difficult to control accurately due to the lack of exploration of its microscopic mechanism. Here, a microdynamics model is constructed for anion exchange dominated by vacancies which revealed the key role of polar solvent in reducing the surface energy barrier of anions through first-principle calculations. Besides, a polar solvent construct in situ anion exchange channels method is proposed. Then, the precise control of anion exchange is demonstrated, and the precise regulation spectrum of the whole red-light range (600-680 nm) is achieved. Finally, various QD LEDs (QLEDs) based on these tunable QDs are fabricated and exhibit excellent photoelectric performance in the main red range (620-680 nm). Among them, the champion QLEDs, have peak external quantum efficiency (EQE) of 16.3% at 633 nm and peak EQE of 18.2% at 646 nm, showing potential in meeting the requirements of display standard.
The harvesting of energy from human motion for portable and wearable electronic devices has received considerable attention. This letter describes a lightweight macrofiber composite (MFC)-based energy harvester for capturing biomechanical energy through the natural motion of the human knee. In the proposed device, a slider-crank mechanism is used to transform the rotary motion of the knee joint to linear motion, and a bending beam is used to transform the linear motion to a bending motion. When walking, a bending deformation is induced in two MFC slices attached to the bending beam, generating electrical energy. To test the performance of the developed device, treadmill tests at various walking speeds and resistive loads are performed. Experimental results show that the lightweight harvester (weighing just 307 g) can generate 1.60 mW without increasing the human effort required for walking. This is expected to significantly promote the usage of biomechanical energy harvesters.
2D puckered materials similar to black phosphorene (BP) have tunable electronic structures, high mobility, and anisotropy, and are expected to become possible candidate channels for post‐silicon field‐effect transistors (FETs). Herein, monolayer α‐CS with puckered structure is evaluated as a promising channel material for sub‐5 nm FETs by using first principle quantum transport simulation. Monolayer α‐CS FETs can satisfy the requirements of the International Technology Roadmap for Semiconductors (ITRS) for high‐performance (HP) and low‐power (LP) applications. The on‐state current can reach 3700 µA µm−1 for HP FET at 5 nm channel length and the on‐off ratio of LP FET is exceeding 107, both superior to those of other 2D channels like BP and InSe. The results suggest that α‐CS as a competitive channel material opens a new avenue for the future electronic technology in the upcoming Internet of Things.
The control of the longitudinal pulsating force and the vibration generated is very important to improve the stealth performance of a submarine. Magnetorheological elastomer (MRE) is a kind of intelligent composite material, whose mechanical properties can be continuously, rapidly and reversibly controlled by an external magnetic field. It can be used as variable-stiffness components in the design of a semi-active dynamic vibration absorber (SDVA), which is one of the effective means of longitudinal vibration control. In this paper, an SDVA is designed based on the MRE’s magnetic-induced variable stiffness characteristic. Firstly, a mechanical model of the propulsion shaft system with the SDVA is proposed, theoretically discussed and numerically validated. Then, the mechanical performance of the MRE under different magnetic fields is tested. In addition, the magnetic circuit and the overall structure of the SDVA are designed. Furthermore, electromagnetic and thermodynamic simulations are carried out to guarantee the structural design. The frequency shift property of the SDVA is found through dynamic simulations and validated by a frequency shift experiment. Lastly, the vibration absorption capacity of the SDVA is investigated. The results show that the magnetorheological effect of the MRE and the frequency shift of the SDVA are obvious; the SDVA has relatively acceptable vibration absorption capacity.
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