The picolinamide-supported tetracoordinated organoboron complexes containing diaryl boronyl segments have been synthesized for the first time. Aryl trifluoroborates were utilized as the BAr2 sources to introduce different aryl motifs with diverse functional groups. The optical experiments discovered these five-membered boron-containing complexes were aggregation-induced emission (AIE) active, thus affording a new class of AIE molecules.
Pre-functionalized benzyne precursors 5, 6 and 10 bearing a phosphoryl group were efficiently synthesized via a phospho-Fries rearrangement reaction on gram scales, and directly proceed various transformations to poly-substituted organophosphorus arenes in high regioselectivity.
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