We report the investigation of full-counting statistics (FCS) of transferred charge and spin in the transient regime where the connection between central scattering region (quantum dot) and leads are turned on at t = 0. A general theoretical formulation for the generating function (GF) is presented using a nonequilibrium Green's function approach for the quantum dot system. In particular, we give a detailed derivation on how to use the method of path integral together with nonequilibrium Green's function technique to obtain the GF of FCS in electron transport systems based on the two-time quantum measurement scheme. The correct long-time limit of the formalism, the Levitov-Lesovik's formula, is obtained. This formalism can be generalized to account for spin transport for the system with noncollinear spin as well as spin-orbit interaction. As an example, we have calculated the GF of spin-polarized transferred charge, transferred spin, as well as the spin transferred torque for a magnetic tunneling junction in the transient regime. The GF is compactly expressed by a functional determinant represented by Green's function and self-energy in the time domain. With this formalism, FCS in spintronics in the transient regime can be studied. We also extend this formalism to the quantum point contact system. For numerical results, we calculate the GF and various cumulants of a double quantum dot system connected by two leads in transient regime. The signature of universal oscillation of FCS is identified. On top of the global oscillation, local oscillations are found in various cumulants as a result of the Rabi oscillation. Finally, the influence of the temperature is also examined.

Waiting time is an important transport quantity that is complementary to average current and its fluctuation. So far all the studies of waiting time distribution (WTD) are limited to steady state transport (either dc or ac). The existing theory can not deal with WTD in the transient regime. In this regard, we develop a theoretical formalism based on Keldysh non-equilibrium Green's functions formalism to study WTD. This theory is suitable for dc, ac, and transient transport and can be used for first principles calculation on realistic systems. We apply this theory to a quantum dot system with a upward bias pulse and calculate cumulants of transferred charge as well as WTD in the transient regime. The oscillatory behavior of WTD is found in the transient regime. We give a general relation between WTD and experimental measured quantity and demonstrate its feasibility for a quantum dot system in the transient regime.

We investigate the full-counting statistics (FCS) of energy flow carried by electrons in the transient regime. Based on two measurement scheme we formulate a non-equilibrium Keldysh Green's function theory to compute the generating function for FCS of energy transport. Specifically, we express the generating function using the path integral along Keldysh contour and obtain exact solution of the generating function using the Grassmann algebra. With this formalism, we calculate the transient energy current and higher order cumulants for both single and double quantum dot (QD) systems in the transient regime. To examine finite bandwidth effect of leads to FCS of energy transport, we have used an exact solvable model with a Lorentizian linewidth where all non-equilibrium Green's functions can be solved exactly in the time domain. It is found that the transient energy current exhibits damped oscillatory behavior. For the single quantum dot system the frequency of oscillation is independent of bandwidth of the leads while the decay rate of the oscillation amplitude is determined by the lifetime of resonant state which increases as the bandwidth decreases. At short times, a universal scaling of maximum amplitude of normalized cumulants is identified for the single QD system. For the double QD system, the damped oscillation of energy current is dominated by Rabi oscillation with frequency approximately proportional to the coupling constant between two quantum dots. In general, the transient energy current increases when the coupling between two QDs is stronger. However, when the interdot coupling is larger than half of the external bias the transient energy current is suppressed significantly. All these results can be understood analytically.

We investigate the full-counting statistics (FCS) of energy transport carried by electrons in molecular junctions for the Anderson-Holstein model in the polaronic regime. Using the two-time quantum measurement scheme, the generating function (GF) for the energy transport is derived and expressed as a Fredholm determinant in terms of Keldysh nonequilibrium Green's function in the time domain. Dressed tunneling approximation is used in decoupling the phonon cloud operator in the polaronic regime. This formalism enables us to analyze the time evolution of energy transport dynamics after a sudden switch-on of the coupling between the dot and the leads towards the stationary state. The steady state energy current cumulant GF in the long time limit is obtained in the energy domain as well. Universal relations for steady state energy current FCS are derived under a finite temperature gradient with zero bias and this enabled us to express the equilibrium energy current cumulant by a linear combination of lower order cumulants. The behaviors of energy current cumulants in steady state under temperature gradient and external bias are numerically studied and explained. The transient dynamics of energy current cumulants is numerically calculated and analyzed. Universal scaling of normalized transient energy cumulants is found under both temperature gradient and external bias.where 0  is the bare electronic energy level, and 0 w is the frequency of the localized vibron. d † (a † ) denotes the electron (phonon) creation operator in the QD. The localized vibron modulates the QD with the electronphonon coupling constant t ep . The Hamiltonians of the leads is given in a compact form