A thorough understanding of hot deformation behavior plays a vital role in determining process parameters of hot working processes. Firstly, uniaxial tensile tests have been performed in the temperature ranges of 150 °C–600 °C and strain rate ranges of 0.0001–0.01s−1 for analyzing the deformation behavior of ASS 304 and ASS 316. The phenomenological-based constitutive models namely modified Fields–Backofen (m-FB) and Khan–Huang–Liang (KHL) have been developed. The prediction capability of these models has been verified with experimental data using various statistical measures. Analysis of statistical measures revealed KHL model has good agreement with experimental flow stress data. Through the flow stresses behavior, the processing maps are established and analyzed according to the dynamic materials model (DMM). In the processing map, the variation of the efficiency of the power dissipation is plotted as a function of temperature and strain rate. The processing maps results have been validated with experimental data.
Amorphous polymer-derived silicon-oxycarbide (SiOC) ceramics have a high theoretical capacity and good structural stability, making them suitable anode materials for lithium-ion batteries. However, SiOC has low electronic conductivity, poor transport properties, low initial Couloumbic efficiency, and limited rate capability. Therefore, there is an urgent need to explore an efficient SiOC-based anode material that could mitigate the abovementioned limitations. In this study, we synthesized carbon-rich SiOC (SiOC-I) and silicon-rich SiOC (SiOC-II) and evaluated their elemental and structural characteristics using a broad spectrum of characterization techniques. Li-ion cells were fabricated for the first time by pairing a buckypaper composed of carbon nanotubes with SiOC-I or SiOC-II as the anode. When mixed with graphene nanoplatelets, the SiOC-II/GNP composites exhibited improved electrochemical performance. High specific capacity (average specific capacity of 744 mAh/g at a 0.1C rate) was achieved with the composite anode (25 wt % SiOC-II and 75% GNP), which was much better than that of monolithic SiOC-I, SiOC-II, or GNPs. This composite also exhibited excellent cycling stability, achieving 344 mAh/g after 260 cycles at a 0.5C rate and high reversibility. The enhanced electrochemical performance is attributed to better electronic conductivity, lower charge-transfer resistance, and short ion diffusion length. Due to their superior electrochemical performance, SiOC/GNP composites with CNT buckypaper as a current collector can be considered a promising anode material for LiBs.
Lithium-ion batteries (LIB) are the energy storage system of choice for the electrification of transportation and portable electronics. They are also being actively considered to meet the need to store...
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