The effect of fluid flow on crystal nucleation in supercooled liquids is not well understood. The variable density and temperature gradients in the liquid make it difficult to study this under terrestrial gravity conditions. Nucleation experiments were therefore made in a microgravity environment using the Electromagnetic Levitation Facility on the International Space Station on a bulk glass-forming Zr57Cu15.4Ni12.6Al10Nb5 (Vit106), as well as Cu50Zr50 and the quasicrystal-forming Ti39.5Zr39.5Ni21 liquids. The maximum supercooling temperatures for each alloy were measured as a function of controlled stirring by applying various combinations of radio-frequency positioner and heater voltages to the water-cooled copper coils. The flow patterns were simulated from the known parameters for the coil and the levitated samples. The maximum nucleation temperatures increased systematically with increased fluid flow in the liquids for Vit106, but stayed nearly unchanged for the other two. These results are consistent with the predictions from the Coupled-Flux model for nucleation.

Pure, low-oxygen zirconium samples have been observed to nucleate a solid phase under conditions during which the sample was expected to remain liquid. This phenomenon was first seen during Spacelab Mission MSL-1R (materials science laboratory) experiments and has since also been observed in the International Space Station (ISS) electromagnetic levitation (EML) facility on a different sample. Current work has been able to replicate these anomalous solidification events under a range of conditions in the ISS MSL-EML facility. The solidification events are not well explained by classical homogeneous or heterogeneous nucleation. The current theory is that collapsing voids in the melt create a local region of high pressure that results in local material being deeply undercooled and a strong driving force for solidification.

During containerless processing, the oscillating drop method can be used to measure the surface tension and viscosity of a levitated melt. Through containerless processing, reactive melts that cannot be measured through conventional methods can be accurately measured; however, the accuracy of this method is dependent on the internal flow within the drop. While laminar flow does not redistribute the momentum of the oscillations, turbulent flow does redistribute the momentum of the flow and, as a result, dominates the damping. As a result, it is important to understand the internal flow behavior and the factors that affect the flow during these experiments. Models are used for the indirect quantification and characterization of the internal flow using the experimental parameters and material properties. In some cases, such as Cu50Zr50, the flow is laminar over the full range of the experiment. In other cases, including Al75Ni25, the sample is dominated by turbulent flow at high temperatures and applied electromagnetic fields, but upon cooling, transitions to laminar flow. Additionally, cases exist in which the flow is fully turbulent over the range of interest and valid measurements using the oscillating drop method are not possible. During the design phase of the experiment, the experimental parameters should be modeled to characterize the flow behavior and ensure a clean experiment.

No abstract