The superimposition of Coulombian long range ion‐ion and non‐Coulombian short range interactions yields mean force potentials which are used to calculate the osmotic coefficients of various organic solvent systems via pair correlation functions. – The agreement with osmotic coefficients from vapor pressure experiments on 22 methanol, ethanol, 2‐propanol, and acetonitrile solutions of alkali metal and tetraalkylammonium salts shows the reliability of the chemical model of electrolyte solutions from infinite dilution to high concentrations.
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