[1] The chemical composition of rocks and soils on Mars analyzed during the Mars Exploration Rover Spirit Mission was determined by X-ray analyses with the Alpha Particle X-Ray Spectrometer (APXS). Details of the data analysis method and the instrument calibration are presented. Measurements performed on Mars to address geometry effects and background contributions are shown. Cross calibration measurements among several instrument sensors and sources are discussed. An unintentional swap of the two flight instruments is evaluated. New concentration data acquired during the first 470 sols of rover Spirit in Gusev Crater are presented. There are two geological regions, the Gusev plains and the Columbia Hills. The plains contain soils that are very similar to previous landing sites on Mars. A meteoritic component in the soil is identified. Rocks in the plains revealed thin weathering rinds. The underlying abraded rock was classified as primitive basalt. One of these rocks contained significant Br that is probably associated with vein-filling material of different composition. One of the trenches showed large subsurface enrichments of Mg, S, and Br. Disturbed soils and rocks in the Columbia Hills revealed different elemental compositions. These rocks are significantly weathered and enriched in mobile elements, such as P, S, Cl, or Br. Even abraded rock surfaces have high Br concentrations. Thus, in contrast to the rocks and soils in the Gusev Plains, the Columbia Hills material shows more significant evidence of ancient aqueous alteration.

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The alpha proton x-ray spectrometer (APXS) on board the rover of the Mars Pathfinder mission measured the chemical composition of six soils and five rocks at the Ares Vallis landing site. The soil analyses show similarity to those determined by the Viking missions. The analyzed rocks were partially covered by dust but otherwise compositionally similar to each other. They are unexpectedly high in silica and potassium, but low in magnesium compared to martian soils and martian meteorites. The analyzed rocks are similar in composition to terrestrial andesites and close to the mean composition of Earth's crust. Addition of a mafic component and reaction products of volcanic gases to the local rock material is necessary to explain the soil composition.

The Alpha Particle X-ray Spectrometer on the Opportunity rover determined major and minor elements of soils and rocks in Meridiani Planum. Chemical compositions differentiate between basaltic rocks, evaporite-rich rocks, basaltic soils, and hematite-rich soils. Although soils are compositionally similar to those at previous landing sites, differences in iron and some minor element concentrations signify the addition of local components. Rocky outcrops are rich in sulfur and variably enriched in bromine relative to chlorine. The interaction with water in the past is indicated by the chemical features in rocks and soils at this site.

The alpha particle x-ray spectrometer on the Spirit rover determined major and minor elements of soils and rocks in Gusev crater in order to unravel the crustal evolution of planet Mars. The composition of soils is similar to those at previous landing sites, as a result of global mixing and distribution by dust storms. Rocks (fresh surfaces exposed by the rock abrasion tool) resemble volcanic rocks of primitive basaltic composition with low intrinsic potassium contents. High abundance of bromine (up to 170 parts per million) in rocks may indicate the alteration of surfaces formed during a past period of aqueous activity in Gusev crater.

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We report the concentrations of K, Th, and Fe on the Martian surface, as determined by the gamma ray spectrometer onboard the 2001 Mars Odyssey spacecraft. K and Th are not uniformly distributed on Mars. K ranges from 2000 to 6000 ppm; Th ranges from 0.2 to 1 ppm. The K/Th ratio varies from 3000 to 9000, but over 95% of the surface has K/Th between 4000 and 7000. Concentrations of K and Th are generally higher than those in basaltic Martian meteorites (K = 200–2600 ppm; Th = 0.1–0.7 ppm), indicating that Martian meteorites are not representative of the bulk crust. The average K/Th in the crust is 5300, consistent with the Wänke‐Dreibus model composition for bulk silicate Mars. Fe concentrations support the idea that bulk Mars is enriched in FeO compared to Earth. The differences in K/Th and FeO between Earth and Mars are consistent with the planets accreting from narrow feeding zones. The concentration of Th on Mars does not vary as much as it does on the Moon (where it ranges from 0.1 to 12 ppm), suggesting that the primary differentiation of Mars differed from that of the Moon. If the average Th concentration (0.6 ppm) of the surface is equal to the average of the entire crust, the crust cannot be thicker than about 118 km. If the crust is about 57 km thick, as suggested by geophysical studies, then about half the Th is concentrated in the crust.

Abstract. Rocks at the Mars Pathfinder site are probably locally derived. Textures on rock surfaces may indicate volcanic, sedimentary, or impact-generated rocks, but aeolian abration and dust coatings prevent unambiguous interpretation. Multispectral imaging has resolved four spectral classes of rocks: gray and red, which occur on different surfaces of the same rocks; pink, which is probably soil crusts; and maroon, which occurs as large boulders, mostly in the far field. Rocks are assigned to two spectral trends based on the position of peak reflectance: the primary spectral trend contains gray, red, and pink rocks; maroon rocks constitute the secondary spectral trend. The spatial pattern of spectral variations observed is oriented along the prevailing wind direction. The primary spectral trend arises from thin ferric coatings of aeolian dust on darker rocks. The secondary spectral trend is apparently due to coating by a different mineral, probably maghemite or ferrihydrite. A chronology based on rock spectra suggests that rounded maroon boulders constitute the oldest petrologic unit (a flood deposit), succeeded by smaller cobbles possibly deposited by impact, and followed by aeolian erosion and deposition. Nearly linear chemical trends in alpha proton X-ray spectrometer rock compositions are interpreted as mixing lines between rock and adhering dust, a conclusion supported by a correlation between sulfur abundance and red/blue spectral ratio. Extrapolations of regression lines to zero sulfur give the composition of a presumed igneous rock. The chemistry and normative mineralogy of the sulfurfree rock resemble common terrestrial volcanic rocks, and its classification corresponds to andesite. Igneous rocks of this composition my occur with clastic sedimentary rocks or impact melts and breccias. However, the spectral mottling expected on conglomerates or breccias is not observed in any APXS-analyzed rocks. Interpretation of the rocks as andesites is complicated by absence of a "1 gm" pyroxene absorption band. Plausible explanations include impact glass, band masking by magnetite, or presence of calcium-and iron-rich pyroxenes and olivine which push the absorption band minimum past the imager's spectral range. The inferred andesitic composition is most sinfilar to terrestrial anorogenic icelandites, formed by fractionation of tholeiitic basaltic magmas. Early melting of a relatively primitive Martian mantle could produce an appropriate parent magma, supporting the ancient age of Patlff•nder rocks inferred from their incorporation in Hesperian flood deposits. Although rocks of andesitic composition at the Patlff•nder site may represent samples of ancient Martian crust, inferences drawn about a necessary role for water or plate tectonics in their petrogenesis are probably unwarranted.