No abstract

Due to higher mechanical demands on technical parts, the application of short fiber reinforced thermoplastics for injection molding is strongly increasing. Therefore, more attention needs to be paid to the optimization of their recycling processes. Mechanical shredding of thermoplastics into granules is a common recycling method within polymer industries. The breaking of polymer chains and reinforcing fibers during this process may affect the material properties. This study presents the effect of ten recycling sequences on four different materials: polypropylene, glass fiber filled polypropylene, carbon fiber filled polypropylene and flax fiber filled polypropylene. Tests indicate that recycling has a negative influence on most of the mechanical properties. Polypropylene without fibers forms an exception as it does not exhibit any significant change in material properties. Glass fiber and carbon fiber reinforced polypropylene show a decrease in stiffness and tensile strength during the recycling steps. The impact strength of carbon and flax fiber reinforced polypropylene increases whereas that of glass fiber reinforced polypropylene decreases.

Recently, a novel two-component injection molding process has been developed for combining thermoplastics with thermoset rubbers. This process is of interest for example when thermoplastic parts include seals which are usually produced out of thermoset rubber. The present study evaluates the influence of different process parameters on the bond strength by means of a half factorial experimental design. The considered process parameters are the mold temperature at the interface, the injection temperature, the injection speed, the holding pressure, and the initial roughness of the thermoplastic part at the later interface. The study indicates a large influence of the mold temperature at the interface. Furthermore, the holding pressure only affects the adhesion strength when it is set too low or when the holding time is too short. The other process parameters have no significant effect on the adhesion strength.

Recently a novel two-component injection molding process has been developed combining thermoplastics with thermoset rubbers. Since the adhesion strength between the two materials strongly depends on the combination of a specific thermoplastic and a thermoset rubber, there is a need to predict their compatibility, defined as the formation of a strong interface. In this study, the wetting behavior of molten thermoplastics on rubber substrates is used to predict their compatibility since wetting is an essential step in the formation of a strong interface. Contact angle measurements at high temperatures showed that the wetting of polypropylene and polyethylene is the best in combination with ethylene propylene diene monomer rubber while nitrile rubber is best wetted by polycarbonate. The subsequent two-component injection molding tests confirm that it is possible to combine these materials. Material combinations with a poor wetting behavior on the other hand are not suitable for two-component injection molding. V C 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46046.

No abstract

No abstract

Multicomponent injection molding often combines a stiff thermoplastic material with a thermoplastic elastomer or thermoplastic vulcanite. Recently, for high‐demanding applications, a novel process has been developed to replace these thermoplastic elastomers or vulcanite with a thermoset rubber, for example, NBR or EPDM. One of the most important properties of a two component product is an adequate adhesion between both components. This paper describes a method, which combines experiments and numerical simulations to predict the adhesion strength between a thermoplastic, semicrystalline HDPE, and an EPDM thermoset rubber. This method uses numerical simulations of the interfacial temperature and the local degree of cure. The local interface temperature is combined with the results of DSC measurements to predict the degree of melting, subsequently linked to the ability to develop adhesive strength. The degree of cure is used to determine the local rubber strength. The combination of the given data will be used to predict interfacial strength. The results obtained by proposed numerical strategy have been successfully validated with experimental data on a simple plate product. POLYM. ENG. SCI., 59:1489–1498 2019. © 2019 Society of Plastics Engineers

Semipermeable membranes were prepared by grafting in the bulk Teflon films with acrylic acid, 4‐vinyl pyridine, and both monomers together by a method of successive grafting. Some kinetic features of these reactions are described. The swelling of the grafted membranes was investigated. In the case of vinylpyridine grafts the swelling properties were also examined after quaternization of the pyridine groups by HCl. A wide variety of membranes can be prepared by the methods described. These membranes exhibit excellent mechanical properties, even in the swollen state, and withstand remarkably well various corrosive media.