Standard commercial L-alanine pellets and specially prepared natural lithium formate monohydrate powder samples of specific granulometry were irradiated in a 60 Co gamma-ray irradiation plant and in the mixed field (thermal neutrons and gamma photons) of a boron neutron capture therapy (BNCT) experimental facility. The γ-doses applied with the 60 Co source range from 0.1 to 50 kGy, while those in the BNCT facility go from ~7 Gy to 150 Gy. The thermal neutron fluences range from 10 12 neutrons cm −2 to 2 10 13 neutrons cm −2 . The irradiation of materials promotes the creation of stable electronic defects (generally free radicals) which constitute paramagnetic centers that can be detected and quantified by electron paramagnetic resonance (EPR). After irradiation, the EPR characterization of the samples was performed by determining the EPR intensity of the spectrum relative to a reference standard constituted by Mn 2+ impurities diluted into a MgO single crystal. As expected, L-alanine has revealed to be largely insensitive to thermal neutrons fluence in the investigated range. On the contrary, it is shown that the EPR intensity of irradiated natural lithium formate monohydrate powders is clearly sensitive to thermal neutrons and has a linear dependence with the γ-dose. We propose a dual dosimeter by combining L-alanine pellets and formate powders that would allow to determine the γ-dose and thermal neutron fluence in a selected position of the BNCT irradiation facility. Moreover, we demonstrate that the 6 Li enrichment that has been proposed in the literature to enhance the performance of lithium-based EPR dosimeters is not crucial in our case. Instead, the natural isotopic abundance of lithium is large enough to obtain a satisfactory sensibility to thermal neutrons in our BNCT facility for fluencies >10 12 neutrons cm −2 .
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